Surface morphology of thin polypyrrole films electrodeposited along aqueous electrolyte–organic liquid interface. Influence of temperature and solvent

Nitrobenzene was found dissimilar to 1,2-dichloroethane and chloroform in electrodeposition of electronically conducting polypyrrole at a water/organic solvent junction by means of the three-phase electrode. Morphologies of the two sides of the potentiostatically deposited, freestanding thin polymer...

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Bibliographic Details
Published in:Journal of solid state electrochemistry 2015-05, Vol.19 (5), p.1293-1300
Main Authors: Wójcik, Kamil, Grzeszczuk, Maria
Format: Article
Language:English
Subjects:
Analytical Chemistry
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Condensed Matter Physics
Electrochemistry
Energy Storage
Original Paper
Physical Chemistry
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Summary:Nitrobenzene was found dissimilar to 1,2-dichloroethane and chloroform in electrodeposition of electronically conducting polypyrrole at a water/organic solvent junction by means of the three-phase electrode. Morphologies of the two sides of the potentiostatically deposited, freestanding thin polymer films differ distinctly which might be of interest for specific applications. A low temperature of the synthesis at the liquid–liquid junction is preferable for attaining the homogeneous surface morphologies of the polymer films.
ISSN:1432-8488
1433-0768
DOI:10.1007/s10008-015-2750-x