Synthesis of novel functionally substituted pyridazines and oxazines

Acetone 1,3-di(phenylhydrazone) reacts with arylidenemalononitriles in the presence of piperidine to give the coressponding 3,3′-carbonylbispyridazine derivatives. Under the same reaction conditions dioxime reacts with arylidenemalononitriles to give the corresponding 3,3′-carbonylbis-1,2-oxazines....

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Published in:Chemistry of heterocyclic compounds (New York, N.Y. 1965) N.Y. 1965), 2008-08, Vol.44 (8), p.985-990
Main Authors: Hammouda, M., Abou Zeid, Z. M., Metwally, M. A.
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Language:English
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Chemistry
Chemistry and Materials Science
Organic Chemistry
Pharmacy
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description Acetone 1,3-di(phenylhydrazone) reacts with arylidenemalononitriles in the presence of piperidine to give the coressponding 3,3′-carbonylbispyridazine derivatives. Under the same reaction conditions dioxime reacts with arylidenemalononitriles to give the corresponding 3,3′-carbonylbis-1,2-oxazines. Dioxime reacts with primary aromatic amines and formalin in a molar ratio of 1:1:2 to give 1-arylidene-3,5-dihydroxyimino-piperidine-4-ones.
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Organic Chemistry
Pharmacy
title Synthesis of novel functionally substituted pyridazines and oxazines
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