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Beckmann rearrangement of 11-deoxo-glycyrrhetic acid 3-ketoxime

A-Homo-4-aza-3-oxo- and 3-cyano-3,4-seco-olean-4,12-diene derivatives of 11-deoxo-glycyrrhetic acid were synthesized by first- and second-order Beckmann rearrangement of 3-hydroxyiminoolean-12-en-30-oic acid methyl ester.

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Bibliographic Details
Published in:Chemistry of natural compounds 2009, Vol.45 (4), p.519-521, Article 519
Main Authors: Mikhailova, L. R, Khudobko, M. V, Baltina, L. A. Jr, Baltina, L. A
Format: Article
Language:English
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Summary:A-Homo-4-aza-3-oxo- and 3-cyano-3,4-seco-olean-4,12-diene derivatives of 11-deoxo-glycyrrhetic acid were synthesized by first- and second-order Beckmann rearrangement of 3-hydroxyiminoolean-12-en-30-oic acid methyl ester.
ISSN:0009-3130
1573-8388
DOI:10.1007/s10600-009-9395-x