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Facile synthesis and lithium storage performance of (NH4)2V3O8 nanoflakes
Single-crystalline (NH 4 ) 2 V 3 O 8 nanoflakes were successfully synthesized by a facile hydrothermal method. We investigated their electrochemical performance for use in lithium ion batteries for the first time. Interestingly, the as-prepared (NH 4 ) 2 V 3 O 8 electrode demonstrated good lithium s...
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| Published in: | Journal of applied electrochemistry 2016-08, Vol.46 (8), p.879-885 |
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| Main Authors: | , , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c240x-8548cc2c193a00f530580ff44f54f5f9a03cb0d91e7851f32b029096c110711a3 |
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| cites | cdi_FETCH-LOGICAL-c240x-8548cc2c193a00f530580ff44f54f5f9a03cb0d91e7851f32b029096c110711a3 |
| container_end_page | 885 |
| container_issue | 8 |
| container_start_page | 879 |
| container_title | Journal of applied electrochemistry |
| container_volume | 46 |
| creator | Xu, Guoqing He, Hanna Wan, Hao Liu, Ruihong Zeng, Xianguang Sun, Dan Huang, Xiaobing Wang, Haiyan |
| description | Single-crystalline (NH
4
)
2
V
3
O
8
nanoflakes were successfully synthesized by a facile hydrothermal method. We investigated their electrochemical performance for use in lithium ion batteries for the first time. Interestingly, the as-prepared (NH
4
)
2
V
3
O
8
electrode demonstrated good lithium storage properties. This material exhibited a high initial discharge capacity of 261.4 mAh g
−1
at a current density of 150 mA g
−1
. Apart from the capacity loss in the first two cycles, the discharge capacity remained relatively stable and a capacity of 215.8 mAh g
−1
was maintained after 30 cycles, indicating good cycling stability. The Coulombic efficiency was close to 100 % during the cycling, revealing that the intercalation/deintercalation of Li ions in this material was highly reversible. The good electrochemical performance of (NH
4
)
2
V
3
O
8
was mainly attributed to its flake-like morphology and intrinsically stable layered structure.
Graphical Abstract |
| doi_str_mv | 10.1007/s10800-016-0973-x |
| format | article |
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4
)
2
V
3
O
8
nanoflakes were successfully synthesized by a facile hydrothermal method. We investigated their electrochemical performance for use in lithium ion batteries for the first time. Interestingly, the as-prepared (NH
4
)
2
V
3
O
8
electrode demonstrated good lithium storage properties. This material exhibited a high initial discharge capacity of 261.4 mAh g
−1
at a current density of 150 mA g
−1
. Apart from the capacity loss in the first two cycles, the discharge capacity remained relatively stable and a capacity of 215.8 mAh g
−1
was maintained after 30 cycles, indicating good cycling stability. The Coulombic efficiency was close to 100 % during the cycling, revealing that the intercalation/deintercalation of Li ions in this material was highly reversible. The good electrochemical performance of (NH
4
)
2
V
3
O
8
was mainly attributed to its flake-like morphology and intrinsically stable layered structure.
Graphical Abstract</description><identifier>ISSN: 0021-891X</identifier><identifier>EISSN: 1572-8838</identifier><identifier>DOI: 10.1007/s10800-016-0973-x</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Chemistry ; Chemistry and Materials Science ; Electrochemistry ; Industrial Chemistry/Chemical Engineering ; Physical Chemistry ; Research Article</subject><ispartof>Journal of applied electrochemistry, 2016-08, Vol.46 (8), p.879-885</ispartof><rights>Springer Science+Business Media Dordrecht 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c240x-8548cc2c193a00f530580ff44f54f5f9a03cb0d91e7851f32b029096c110711a3</citedby><cites>FETCH-LOGICAL-c240x-8548cc2c193a00f530580ff44f54f5f9a03cb0d91e7851f32b029096c110711a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Xu, Guoqing</creatorcontrib><creatorcontrib>He, Hanna</creatorcontrib><creatorcontrib>Wan, Hao</creatorcontrib><creatorcontrib>Liu, Ruihong</creatorcontrib><creatorcontrib>Zeng, Xianguang</creatorcontrib><creatorcontrib>Sun, Dan</creatorcontrib><creatorcontrib>Huang, Xiaobing</creatorcontrib><creatorcontrib>Wang, Haiyan</creatorcontrib><title>Facile synthesis and lithium storage performance of (NH4)2V3O8 nanoflakes</title><title>Journal of applied electrochemistry</title><addtitle>J Appl Electrochem</addtitle><description>Single-crystalline (NH
4
)
2
V
3
O
8
nanoflakes were successfully synthesized by a facile hydrothermal method. We investigated their electrochemical performance for use in lithium ion batteries for the first time. Interestingly, the as-prepared (NH
4
)
2
V
3
O
8
electrode demonstrated good lithium storage properties. This material exhibited a high initial discharge capacity of 261.4 mAh g
−1
at a current density of 150 mA g
−1
. Apart from the capacity loss in the first two cycles, the discharge capacity remained relatively stable and a capacity of 215.8 mAh g
−1
was maintained after 30 cycles, indicating good cycling stability. The Coulombic efficiency was close to 100 % during the cycling, revealing that the intercalation/deintercalation of Li ions in this material was highly reversible. The good electrochemical performance of (NH
4
)
2
V
3
O
8
was mainly attributed to its flake-like morphology and intrinsically stable layered structure.
Graphical Abstract</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Electrochemistry</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Physical Chemistry</subject><subject>Research Article</subject><issn>0021-891X</issn><issn>1572-8838</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEURYMoWKs_wF2Wuoi-l8xHspRibaHYjYq7kKZJO3UmU5IptP_eKeNaeHA371wuh5B7hCcEKJ8TggRggAUDVQp2vCAjzEvOpBTykowAODKp8Pua3KS0AwDFi2xE5lNjq9rRdArd1qUqURPWtK66bXVoaOraaDaO7l30bWxMsI62nj68z7JH_iWWkgYTWl-bH5duyZU3dXJ3fzkmn9PXj8mMLZZv88nLglmewZHJPJPWcotKGACfC8gleJ9lPu_PKwPCrmCt0JUyRy_4CrgCVVhEKBGNGBMcem1sU4rO632sGhNPGkGfXejBhe5d6LMLfewZPjCp_w0bF_WuPcTQz_wH-gWcxWC5</recordid><startdate>20160801</startdate><enddate>20160801</enddate><creator>Xu, Guoqing</creator><creator>He, Hanna</creator><creator>Wan, Hao</creator><creator>Liu, Ruihong</creator><creator>Zeng, Xianguang</creator><creator>Sun, Dan</creator><creator>Huang, Xiaobing</creator><creator>Wang, Haiyan</creator><general>Springer Netherlands</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20160801</creationdate><title>Facile synthesis and lithium storage performance of (NH4)2V3O8 nanoflakes</title><author>Xu, Guoqing ; He, Hanna ; Wan, Hao ; Liu, Ruihong ; Zeng, Xianguang ; Sun, Dan ; Huang, Xiaobing ; Wang, Haiyan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c240x-8548cc2c193a00f530580ff44f54f5f9a03cb0d91e7851f32b029096c110711a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Electrochemistry</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Physical Chemistry</topic><topic>Research Article</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Guoqing</creatorcontrib><creatorcontrib>He, Hanna</creatorcontrib><creatorcontrib>Wan, Hao</creatorcontrib><creatorcontrib>Liu, Ruihong</creatorcontrib><creatorcontrib>Zeng, Xianguang</creatorcontrib><creatorcontrib>Sun, Dan</creatorcontrib><creatorcontrib>Huang, Xiaobing</creatorcontrib><creatorcontrib>Wang, Haiyan</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of applied electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Guoqing</au><au>He, Hanna</au><au>Wan, Hao</au><au>Liu, Ruihong</au><au>Zeng, Xianguang</au><au>Sun, Dan</au><au>Huang, Xiaobing</au><au>Wang, Haiyan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Facile synthesis and lithium storage performance of (NH4)2V3O8 nanoflakes</atitle><jtitle>Journal of applied electrochemistry</jtitle><stitle>J Appl Electrochem</stitle><date>2016-08-01</date><risdate>2016</risdate><volume>46</volume><issue>8</issue><spage>879</spage><epage>885</epage><pages>879-885</pages><issn>0021-891X</issn><eissn>1572-8838</eissn><abstract>Single-crystalline (NH
4
)
2
V
3
O
8
nanoflakes were successfully synthesized by a facile hydrothermal method. We investigated their electrochemical performance for use in lithium ion batteries for the first time. Interestingly, the as-prepared (NH
4
)
2
V
3
O
8
electrode demonstrated good lithium storage properties. This material exhibited a high initial discharge capacity of 261.4 mAh g
−1
at a current density of 150 mA g
−1
. Apart from the capacity loss in the first two cycles, the discharge capacity remained relatively stable and a capacity of 215.8 mAh g
−1
was maintained after 30 cycles, indicating good cycling stability. The Coulombic efficiency was close to 100 % during the cycling, revealing that the intercalation/deintercalation of Li ions in this material was highly reversible. The good electrochemical performance of (NH
4
)
2
V
3
O
8
was mainly attributed to its flake-like morphology and intrinsically stable layered structure.
Graphical Abstract</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10800-016-0973-x</doi><tpages>7</tpages></addata></record> |
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| ispartof | Journal of applied electrochemistry, 2016-08, Vol.46 (8), p.879-885 |
| issn | 0021-891X 1572-8838 |
| language | eng |
| recordid | cdi_crossref_primary_10_1007_s10800_016_0973_x |
| source | Springer Nature:Jisc Collections:Springer Nature Read and Publish 2023-2025: Springer Reading List |
| subjects | Chemistry Chemistry and Materials Science Electrochemistry Industrial Chemistry/Chemical Engineering Physical Chemistry Research Article |
| title | Facile synthesis and lithium storage performance of (NH4)2V3O8 nanoflakes |
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