Effect of metallic nanoparticle sizes on the local field near their surface

We have used numerical calculations based on Mie theory to analyze the near field distribution patterns for 4–150 nm spherical silver nanoparticles (nanospheres). We have shown that as the nanoparticle sizes increase, the region where “hot spots” are concentrated is shifted to the forward hemisphere...

Full description

Saved in:
Bibliographic Details
Published in:Journal of applied spectroscopy 2008-11, Vol.75 (6), p.832-838
Main Authors: Dynich, R. A., Ponyavina, A. N.
Format: Article
Language:English
Subjects:
Analytical Chemistry
Atomic/Molecular Structure and Spectra
Physics
Physics and Astronomy
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:We have used numerical calculations based on Mie theory to analyze the near field distribution patterns for 4–150 nm spherical silver nanoparticles (nanospheres). We have shown that as the nanoparticle sizes increase, the region where “hot spots” are concentrated is shifted to the forward hemisphere. We have observed a nonmonotonic dependence of the maximum attainable local field enhancement factor on the size of the silver nanospheres. We have determined a correlation between the optimal nanosphere size for the maximum attainable local field enhancement factor and the optical absorption efficiency factor. We have established a nonmonotonic dependence of the optimal size of the nanoparticles and the maximum attainable local field enhancement factor on the refractive index of the surrounding medium.
ISSN:0021-9037
1573-8647
DOI:10.1007/s10812-009-9125-y