Effect of heat-treatment on the structural and optical properties of Cu2S thin films deposited by CBD method

• Published in: Journal of materials science. Materials in electronics 2014-02, Vol.25 (2), p.824-831
• Main Authors: Vasuhi, A., Xavier, R. John, Chandramohan, R., Muthukumaran, S., Dhanabalan, K., Ashokkumar, M., Parameswaran, P.
• Format: Article
• Language: English
• Subjects: Characterization and Evaluation of Materials; Chemistry and Materials Science; Materials Science; Optical and Electronic Materials
• ISSN: 0957-4522; 1573-482X
• DOI: 10.1007/s10854-013-1652-x

Semiconducting Cu 2 S thin films were successfully deposited on glass substrate under three different conditions such as as-deposited, post heat-treated and pre heated precursor solution by chemical bath deposition technique. Structural and optical properties of the films were characterized by X-ray diffraction (XRD), scanning electron microscope, energy dispersive X-ray (EDX) analysis and UV–Visible spectrophotometer. The XRD spectra showed the amorphous nature of thin films with hexagonal structure. The d value and micro strain increased and the average crystallite size decreased from 1.9 to 1.4 and 1.3 nm respectively when the as-deposited film was subjected to post heat-treatment and the precursor solution temperature was elevated. The presence of more nucleation centers and fast reaction rate decreased the average crystallite size in films grown with pre heated precursor solution. The noticed blue shift in energy gap and the shift of XRD peak position towards the lower 2θ side by heat-treatment could be considered as a sign of the quantum confined effect due to the formation of the nano-sized Cu 2 S crystals on the surface. The transmittance of heat-treated Cu 2 S films in the visible region matched the phototropic vision of human eye (~600 nm) which makes them suitable for solar control coatings on architectural windows and automobiles in the regions with warm climates. Low transmittance behaviour of pre heated Cu 2 S films could be used for anti dazzling coatings for car windscreens and driving mirrors to reduce the dazzling effects of light at night. EDX spectra showed the chemical purity of the films. The observed broad absorption and blue shift in band gap of the heat-treated films were due to quantum confinement effect. Fourier transform infrared studies were also carried out and the results are presented.