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Synthesis, Spectroscopic Studies and X-ray Crystal Structures of New Pyrazoline and Pyrazole Derivatives
The synthesis and characterization of some pyrazoline compounds of 1,3-diketones with hydrazine derivatives, namely, 1-( S -benzyldithiocarbazate)-3-methyl-5-phenyl-5-hydroxypyrazoline ( 1 ); 1-(2-thiophenecarboxylic)-3-methyl-5-phenyl-5-hydroxypyrazoline ( 2 ); 1-(2-thiophenecarboxylic)-3,5-dimethy...
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| Published in: | Journal of chemical crystallography 2011-03, Vol.41 (3), p.401-408 |
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| cites | cdi_FETCH-LOGICAL-c288t-52321a16ac73a13bd3b764f37557a1dbb6854c7a8ea1efa93fd35bd9c7d283a53 |
| container_end_page | 408 |
| container_issue | 3 |
| container_start_page | 401 |
| container_title | Journal of chemical crystallography |
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| creator | de Sousa, Gerimário F. Gatto, Claudia C. Resck, Inês S. Deflon, Victor M. |
| description | The synthesis and characterization of some pyrazoline compounds of 1,3-diketones with hydrazine derivatives, namely, 1-(
S
-benzyldithiocarbazate)-3-methyl-5-phenyl-5-hydroxypyrazoline (
1
); 1-(2-thiophenecarboxylic)-3-methyl-5-phenyl-5-hydroxypyrazoline (
2
); 1-(2-thiophenecarboxylic)-3,5-dimethyl-5-hydroxypyrazoline (
3
); 1-(
S
-benzyldithiocarbazato)-3-methyl-5-phenylpyrazole (
4
); 1-(2-thiophenecarboxylic)-3-methyl-5-phenylpyrazole (
5
) and 1-(
S
-benzyldithiocarbazate)-3,5-dimethylpyrazole (
6
) are reported. Studies by IR, (
1
H,
13
C)-NMR spectroscopies and single crystal X-ray diffraction revealed that compounds (
1
)
,
(
2
) and (
3
) are formed as pyrazoline, whereas (
4
) and (
5
) are formed as pyrazole derivatives only under acidic conditions. Compound (
1
) crystallizes in orthorhombic
P
2
1
2
1
2
1
,
a
= 6.38960(10) Å,
b
= 12.9176(3) Å,
c
= 21.2552(5) Å, (
2
) crystallizes in monoclinic,
P
2
1
/
n
,
a
= 11.3617(2) Å,
b
= 8.4988(2) Å,
c
= 92.8900(10) Å and
β
= 92.8900(5)°, (
3
) crystallizes in monoclinic,
C
2/
c
,
a
= 15.9500(5) Å,
b
= 9.3766(3) Å,
c
= 16.6910(5) Å and
β
= 113.825(2)°, (
4
) crystallizes in monoclinic,
P
2
1
/
c
,
a
= 15.228(4) Å,
b
= 5.5714(13) Å,
c
= 19.956(5) Å and
β
= 91.575(7)° and (
6
) crystallizes in orthorhombic,
P
2
1
2
1
2
1
,
a
= 5.3920(2) Å,
b
= 11.2074(5) Å,
c
= 21.885(1) Å. The (
3
) derivative represents the first pyrazoline compound prepared from 2,4-pentanedione and characterized crystallographically.
Graphical Abstract
The synthesis and characterization of some pyrazoline compounds of 1,3-diketones with hydrazine derivatives, namely, 1-(
S
-benzyldithiocarbazate)-3-methyl-5-phenyl-5-hydroxypyrazoline (
1
); 1-(2-thiophenecarboxylic)-3-methyl-5-phenyl-5-hydroxypyrazoline (
2
); 1-(2-thiophenecarboxylic)-3,5-dimethyl-5-hydroxypyrazoline (
3
); 1-(
S
-benzyldithiocarbazato)-3-methyl-5-phenylpyrazole (
4
); 1-(2-thiophenecarboxylic)-3-methyl-5-phenylpyrazole (
5
) and 1-(
S
-benzyldithiocarbazate)-3,5-dimethylpyrazole (
6
) are reported. Studies by IR, (
1
H,
13
C)-NMR spectroscopies and single crystal X-ray diffraction revealed that compounds (
1
)
,
(
2
) and (
3
) are formed as pyrazoline, whereas (
4
) and (
5
) are formed as pyrazole derivatives only under acidic conditions. Compound (
1
) crystallizes in orthorhombic
P
2
1
2
1
2
1
,
a
= 6.38960(10) Å,
b
= 12.9176(3) Å,
c
= 21.2552(5) Å, (
2
) crystallizes in monoclinic,
P
2
1
/
n
,
a
= 11.3617(2) Å,
b
= 8.4988(2) Å,
c
= 92.89 |
| doi_str_mv | 10.1007/s10870-010-9896-2 |
| format | article |
| fullrecord | <record><control><sourceid>crossref_sprin</sourceid><recordid>TN_cdi_crossref_primary_10_1007_s10870_010_9896_2</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1007_s10870_010_9896_2</sourcerecordid><originalsourceid>FETCH-LOGICAL-c288t-52321a16ac73a13bd3b764f37557a1dbb6854c7a8ea1efa93fd35bd9c7d283a53</originalsourceid><addsrcrecordid>eNp9kMtOwzAQRS0EEqXwAez8ARj8iGNnicpTqgCpILGzJrZDU5Wksp2i8PW4lDWrmdHcO5p7EDpn9JJRqq4io1pRQhklla5Kwg_QhEnFidayOMw9VQVhsuDH6CTGFaW00lxN0HIxdmnpYxsv8GLjbQp9tP2mtXiRBtf6iKFz-J0EGPEsjDHBOm_CYNMQ8rJv8JP_wi9jgO9-3Xb-V_43enzjQ7uF1G59PEVHDayjP_urU_R2d_s6eyDz5_vH2fWcWK51IpILzoCVYJUAJmonalUWjVBSKmCursucxyrQHphvoBKNE7J2lVWOawFSTBHb37U5SQy-MZvQfkIYDaNmh8rsUZmMyuxQGZ49fO-JWdt9-GBW_RC6_OY_ph8Dwm5U</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis, Spectroscopic Studies and X-ray Crystal Structures of New Pyrazoline and Pyrazole Derivatives</title><source>Springer Link</source><creator>de Sousa, Gerimário F. ; Gatto, Claudia C. ; Resck, Inês S. ; Deflon, Victor M.</creator><creatorcontrib>de Sousa, Gerimário F. ; Gatto, Claudia C. ; Resck, Inês S. ; Deflon, Victor M.</creatorcontrib><description>The synthesis and characterization of some pyrazoline compounds of 1,3-diketones with hydrazine derivatives, namely, 1-(
S
-benzyldithiocarbazate)-3-methyl-5-phenyl-5-hydroxypyrazoline (
1
); 1-(2-thiophenecarboxylic)-3-methyl-5-phenyl-5-hydroxypyrazoline (
2
); 1-(2-thiophenecarboxylic)-3,5-dimethyl-5-hydroxypyrazoline (
3
); 1-(
S
-benzyldithiocarbazato)-3-methyl-5-phenylpyrazole (
4
); 1-(2-thiophenecarboxylic)-3-methyl-5-phenylpyrazole (
5
) and 1-(
S
-benzyldithiocarbazate)-3,5-dimethylpyrazole (
6
) are reported. Studies by IR, (
1
H,
13
C)-NMR spectroscopies and single crystal X-ray diffraction revealed that compounds (
1
)
,
(
2
) and (
3
) are formed as pyrazoline, whereas (
4
) and (
5
) are formed as pyrazole derivatives only under acidic conditions. Compound (
1
) crystallizes in orthorhombic
P
2
1
2
1
2
1
,
a
= 6.38960(10) Å,
b
= 12.9176(3) Å,
c
= 21.2552(5) Å, (
2
) crystallizes in monoclinic,
P
2
1
/
n
,
a
= 11.3617(2) Å,
b
= 8.4988(2) Å,
c
= 92.8900(10) Å and
β
= 92.8900(5)°, (
3
) crystallizes in monoclinic,
C
2/
c
,
a
= 15.9500(5) Å,
b
= 9.3766(3) Å,
c
= 16.6910(5) Å and
β
= 113.825(2)°, (
4
) crystallizes in monoclinic,
P
2
1
/
c
,
a
= 15.228(4) Å,
b
= 5.5714(13) Å,
c
= 19.956(5) Å and
β
= 91.575(7)° and (
6
) crystallizes in orthorhombic,
P
2
1
2
1
2
1
,
a
= 5.3920(2) Å,
b
= 11.2074(5) Å,
c
= 21.885(1) Å. The (
3
) derivative represents the first pyrazoline compound prepared from 2,4-pentanedione and characterized crystallographically.
Graphical Abstract
The synthesis and characterization of some pyrazoline compounds of 1,3-diketones with hydrazine derivatives, namely, 1-(
S
-benzyldithiocarbazate)-3-methyl-5-phenyl-5-hydroxypyrazoline (
1
); 1-(2-thiophenecarboxylic)-3-methyl-5-phenyl-5-hydroxypyrazoline (
2
); 1-(2-thiophenecarboxylic)-3,5-dimethyl-5-hydroxypyrazoline (
3
); 1-(
S
-benzyldithiocarbazato)-3-methyl-5-phenylpyrazole (
4
); 1-(2-thiophenecarboxylic)-3-methyl-5-phenylpyrazole (
5
) and 1-(
S
-benzyldithiocarbazate)-3,5-dimethylpyrazole (
6
) are reported. Studies by IR, (
1
H,
13
C)-NMR spectroscopies and single crystal X-ray diffraction revealed that compounds (
1
)
,
(
2
) and (
3
) are formed as pyrazoline, whereas (
4
) and (
5
) are formed as pyrazole derivatives only under acidic conditions. Compound (
1
) crystallizes in orthorhombic
P
2
1
2
1
2
1
,
a
= 6.38960(10) Å,
b
= 12.9176(3) Å,
c
= 21.2552(5) Å, (
2
) crystallizes in monoclinic,
P
2
1
/
n
,
a
= 11.3617(2) Å,
b
= 8.4988(2) Å,
c
= 92.8900(10) Å and
β
= 92.8900(5)°, (
3
) crystallizes in monoclinic,
C
2/
c
,
a
= 15.9500(5) Å,
b
= 9.3766(3) Å,
c
= 16.6910(5) Å and
β
= 113.825(2)°, (
4
) crystallizes in monoclinic,
P
2
1
/
c
,
a
= 15.228(4) Å,
b
= 5.5714(13) Å,
c
= 19.956(5) Å and
β
= 91.575(7)° and (
6
) crystallizes in orthorhombic,
P
2
1
2
1
2
1
,
a
= 5.3920(2) Å,
b
= 11.2074(5) Å,
c
= 21.885(1) Å. The (
3
) derivative represents the first pyrazoline compound prepared from 2,4-pentanedione and characterized crystallographically.</description><identifier>ISSN: 1074-1542</identifier><identifier>EISSN: 1572-8854</identifier><identifier>DOI: 10.1007/s10870-010-9896-2</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Chemistry ; Chemistry and Materials Science ; Crystallography and Scattering Methods ; Inorganic Chemistry ; Organometallic Chemistry ; Original Paper ; Physical Chemistry</subject><ispartof>Journal of chemical crystallography, 2011-03, Vol.41 (3), p.401-408</ispartof><rights>Springer Science+Business Media, LLC 2010</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c288t-52321a16ac73a13bd3b764f37557a1dbb6854c7a8ea1efa93fd35bd9c7d283a53</citedby><cites>FETCH-LOGICAL-c288t-52321a16ac73a13bd3b764f37557a1dbb6854c7a8ea1efa93fd35bd9c7d283a53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>de Sousa, Gerimário F.</creatorcontrib><creatorcontrib>Gatto, Claudia C.</creatorcontrib><creatorcontrib>Resck, Inês S.</creatorcontrib><creatorcontrib>Deflon, Victor M.</creatorcontrib><title>Synthesis, Spectroscopic Studies and X-ray Crystal Structures of New Pyrazoline and Pyrazole Derivatives</title><title>Journal of chemical crystallography</title><addtitle>J Chem Crystallogr</addtitle><description>The synthesis and characterization of some pyrazoline compounds of 1,3-diketones with hydrazine derivatives, namely, 1-(
S
-benzyldithiocarbazate)-3-methyl-5-phenyl-5-hydroxypyrazoline (
1
); 1-(2-thiophenecarboxylic)-3-methyl-5-phenyl-5-hydroxypyrazoline (
2
); 1-(2-thiophenecarboxylic)-3,5-dimethyl-5-hydroxypyrazoline (
3
); 1-(
S
-benzyldithiocarbazato)-3-methyl-5-phenylpyrazole (
4
); 1-(2-thiophenecarboxylic)-3-methyl-5-phenylpyrazole (
5
) and 1-(
S
-benzyldithiocarbazate)-3,5-dimethylpyrazole (
6
) are reported. Studies by IR, (
1
H,
13
C)-NMR spectroscopies and single crystal X-ray diffraction revealed that compounds (
1
)
,
(
2
) and (
3
) are formed as pyrazoline, whereas (
4
) and (
5
) are formed as pyrazole derivatives only under acidic conditions. Compound (
1
) crystallizes in orthorhombic
P
2
1
2
1
2
1
,
a
= 6.38960(10) Å,
b
= 12.9176(3) Å,
c
= 21.2552(5) Å, (
2
) crystallizes in monoclinic,
P
2
1
/
n
,
a
= 11.3617(2) Å,
b
= 8.4988(2) Å,
c
= 92.8900(10) Å and
β
= 92.8900(5)°, (
3
) crystallizes in monoclinic,
C
2/
c
,
a
= 15.9500(5) Å,
b
= 9.3766(3) Å,
c
= 16.6910(5) Å and
β
= 113.825(2)°, (
4
) crystallizes in monoclinic,
P
2
1
/
c
,
a
= 15.228(4) Å,
b
= 5.5714(13) Å,
c
= 19.956(5) Å and
β
= 91.575(7)° and (
6
) crystallizes in orthorhombic,
P
2
1
2
1
2
1
,
a
= 5.3920(2) Å,
b
= 11.2074(5) Å,
c
= 21.885(1) Å. The (
3
) derivative represents the first pyrazoline compound prepared from 2,4-pentanedione and characterized crystallographically.
Graphical Abstract
The synthesis and characterization of some pyrazoline compounds of 1,3-diketones with hydrazine derivatives, namely, 1-(
S
-benzyldithiocarbazate)-3-methyl-5-phenyl-5-hydroxypyrazoline (
1
); 1-(2-thiophenecarboxylic)-3-methyl-5-phenyl-5-hydroxypyrazoline (
2
); 1-(2-thiophenecarboxylic)-3,5-dimethyl-5-hydroxypyrazoline (
3
); 1-(
S
-benzyldithiocarbazato)-3-methyl-5-phenylpyrazole (
4
); 1-(2-thiophenecarboxylic)-3-methyl-5-phenylpyrazole (
5
) and 1-(
S
-benzyldithiocarbazate)-3,5-dimethylpyrazole (
6
) are reported. Studies by IR, (
1
H,
13
C)-NMR spectroscopies and single crystal X-ray diffraction revealed that compounds (
1
)
,
(
2
) and (
3
) are formed as pyrazoline, whereas (
4
) and (
5
) are formed as pyrazole derivatives only under acidic conditions. Compound (
1
) crystallizes in orthorhombic
P
2
1
2
1
2
1
,
a
= 6.38960(10) Å,
b
= 12.9176(3) Å,
c
= 21.2552(5) Å, (
2
) crystallizes in monoclinic,
P
2
1
/
n
,
a
= 11.3617(2) Å,
b
= 8.4988(2) Å,
c
= 92.8900(10) Å and
β
= 92.8900(5)°, (
3
) crystallizes in monoclinic,
C
2/
c
,
a
= 15.9500(5) Å,
b
= 9.3766(3) Å,
c
= 16.6910(5) Å and
β
= 113.825(2)°, (
4
) crystallizes in monoclinic,
P
2
1
/
c
,
a
= 15.228(4) Å,
b
= 5.5714(13) Å,
c
= 19.956(5) Å and
β
= 91.575(7)° and (
6
) crystallizes in orthorhombic,
P
2
1
2
1
2
1
,
a
= 5.3920(2) Å,
b
= 11.2074(5) Å,
c
= 21.885(1) Å. The (
3
) derivative represents the first pyrazoline compound prepared from 2,4-pentanedione and characterized crystallographically.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystallography and Scattering Methods</subject><subject>Inorganic Chemistry</subject><subject>Organometallic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><issn>1074-1542</issn><issn>1572-8854</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAQRS0EEqXwAez8ARj8iGNnicpTqgCpILGzJrZDU5Wksp2i8PW4lDWrmdHcO5p7EDpn9JJRqq4io1pRQhklla5Kwg_QhEnFidayOMw9VQVhsuDH6CTGFaW00lxN0HIxdmnpYxsv8GLjbQp9tP2mtXiRBtf6iKFz-J0EGPEsjDHBOm_CYNMQ8rJv8JP_wi9jgO9-3Xb-V_43enzjQ7uF1G59PEVHDayjP_urU_R2d_s6eyDz5_vH2fWcWK51IpILzoCVYJUAJmonalUWjVBSKmCursucxyrQHphvoBKNE7J2lVWOawFSTBHb37U5SQy-MZvQfkIYDaNmh8rsUZmMyuxQGZ49fO-JWdt9-GBW_RC6_OY_ph8Dwm5U</recordid><startdate>20110301</startdate><enddate>20110301</enddate><creator>de Sousa, Gerimário F.</creator><creator>Gatto, Claudia C.</creator><creator>Resck, Inês S.</creator><creator>Deflon, Victor M.</creator><general>Springer US</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20110301</creationdate><title>Synthesis, Spectroscopic Studies and X-ray Crystal Structures of New Pyrazoline and Pyrazole Derivatives</title><author>de Sousa, Gerimário F. ; Gatto, Claudia C. ; Resck, Inês S. ; Deflon, Victor M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c288t-52321a16ac73a13bd3b764f37557a1dbb6854c7a8ea1efa93fd35bd9c7d283a53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystallography and Scattering Methods</topic><topic>Inorganic Chemistry</topic><topic>Organometallic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>de Sousa, Gerimário F.</creatorcontrib><creatorcontrib>Gatto, Claudia C.</creatorcontrib><creatorcontrib>Resck, Inês S.</creatorcontrib><creatorcontrib>Deflon, Victor M.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of chemical crystallography</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>de Sousa, Gerimário F.</au><au>Gatto, Claudia C.</au><au>Resck, Inês S.</au><au>Deflon, Victor M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, Spectroscopic Studies and X-ray Crystal Structures of New Pyrazoline and Pyrazole Derivatives</atitle><jtitle>Journal of chemical crystallography</jtitle><stitle>J Chem Crystallogr</stitle><date>2011-03-01</date><risdate>2011</risdate><volume>41</volume><issue>3</issue><spage>401</spage><epage>408</epage><pages>401-408</pages><issn>1074-1542</issn><eissn>1572-8854</eissn><abstract>The synthesis and characterization of some pyrazoline compounds of 1,3-diketones with hydrazine derivatives, namely, 1-(
S
-benzyldithiocarbazate)-3-methyl-5-phenyl-5-hydroxypyrazoline (
1
); 1-(2-thiophenecarboxylic)-3-methyl-5-phenyl-5-hydroxypyrazoline (
2
); 1-(2-thiophenecarboxylic)-3,5-dimethyl-5-hydroxypyrazoline (
3
); 1-(
S
-benzyldithiocarbazato)-3-methyl-5-phenylpyrazole (
4
); 1-(2-thiophenecarboxylic)-3-methyl-5-phenylpyrazole (
5
) and 1-(
S
-benzyldithiocarbazate)-3,5-dimethylpyrazole (
6
) are reported. Studies by IR, (
1
H,
13
C)-NMR spectroscopies and single crystal X-ray diffraction revealed that compounds (
1
)
,
(
2
) and (
3
) are formed as pyrazoline, whereas (
4
) and (
5
) are formed as pyrazole derivatives only under acidic conditions. Compound (
1
) crystallizes in orthorhombic
P
2
1
2
1
2
1
,
a
= 6.38960(10) Å,
b
= 12.9176(3) Å,
c
= 21.2552(5) Å, (
2
) crystallizes in monoclinic,
P
2
1
/
n
,
a
= 11.3617(2) Å,
b
= 8.4988(2) Å,
c
= 92.8900(10) Å and
β
= 92.8900(5)°, (
3
) crystallizes in monoclinic,
C
2/
c
,
a
= 15.9500(5) Å,
b
= 9.3766(3) Å,
c
= 16.6910(5) Å and
β
= 113.825(2)°, (
4
) crystallizes in monoclinic,
P
2
1
/
c
,
a
= 15.228(4) Å,
b
= 5.5714(13) Å,
c
= 19.956(5) Å and
β
= 91.575(7)° and (
6
) crystallizes in orthorhombic,
P
2
1
2
1
2
1
,
a
= 5.3920(2) Å,
b
= 11.2074(5) Å,
c
= 21.885(1) Å. The (
3
) derivative represents the first pyrazoline compound prepared from 2,4-pentanedione and characterized crystallographically.
Graphical Abstract
The synthesis and characterization of some pyrazoline compounds of 1,3-diketones with hydrazine derivatives, namely, 1-(
S
-benzyldithiocarbazate)-3-methyl-5-phenyl-5-hydroxypyrazoline (
1
); 1-(2-thiophenecarboxylic)-3-methyl-5-phenyl-5-hydroxypyrazoline (
2
); 1-(2-thiophenecarboxylic)-3,5-dimethyl-5-hydroxypyrazoline (
3
); 1-(
S
-benzyldithiocarbazato)-3-methyl-5-phenylpyrazole (
4
); 1-(2-thiophenecarboxylic)-3-methyl-5-phenylpyrazole (
5
) and 1-(
S
-benzyldithiocarbazate)-3,5-dimethylpyrazole (
6
) are reported. Studies by IR, (
1
H,
13
C)-NMR spectroscopies and single crystal X-ray diffraction revealed that compounds (
1
)
,
(
2
) and (
3
) are formed as pyrazoline, whereas (
4
) and (
5
) are formed as pyrazole derivatives only under acidic conditions. Compound (
1
) crystallizes in orthorhombic
P
2
1
2
1
2
1
,
a
= 6.38960(10) Å,
b
= 12.9176(3) Å,
c
= 21.2552(5) Å, (
2
) crystallizes in monoclinic,
P
2
1
/
n
,
a
= 11.3617(2) Å,
b
= 8.4988(2) Å,
c
= 92.8900(10) Å and
β
= 92.8900(5)°, (
3
) crystallizes in monoclinic,
C
2/
c
,
a
= 15.9500(5) Å,
b
= 9.3766(3) Å,
c
= 16.6910(5) Å and
β
= 113.825(2)°, (
4
) crystallizes in monoclinic,
P
2
1
/
c
,
a
= 15.228(4) Å,
b
= 5.5714(13) Å,
c
= 19.956(5) Å and
β
= 91.575(7)° and (
6
) crystallizes in orthorhombic,
P
2
1
2
1
2
1
,
a
= 5.3920(2) Å,
b
= 11.2074(5) Å,
c
= 21.885(1) Å. The (
3
) derivative represents the first pyrazoline compound prepared from 2,4-pentanedione and characterized crystallographically.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10870-010-9896-2</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1074-1542 |
| ispartof | Journal of chemical crystallography, 2011-03, Vol.41 (3), p.401-408 |
| issn | 1074-1542 1572-8854 |
| language | eng |
| recordid | cdi_crossref_primary_10_1007_s10870_010_9896_2 |
| source | Springer Link |
| subjects | Chemistry Chemistry and Materials Science Crystallography and Scattering Methods Inorganic Chemistry Organometallic Chemistry Original Paper Physical Chemistry |
| title | Synthesis, Spectroscopic Studies and X-ray Crystal Structures of New Pyrazoline and Pyrazole Derivatives |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T20%3A25%3A26IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref_sprin&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis,%20Spectroscopic%20Studies%20and%20X-ray%20Crystal%20Structures%20of%20New%20Pyrazoline%20and%20Pyrazole%20Derivatives&rft.jtitle=Journal%20of%20chemical%20crystallography&rft.au=de%20Sousa,%20Gerim%C3%A1rio%20F.&rft.date=2011-03-01&rft.volume=41&rft.issue=3&rft.spage=401&rft.epage=408&rft.pages=401-408&rft.issn=1074-1542&rft.eissn=1572-8854&rft_id=info:doi/10.1007/s10870-010-9896-2&rft_dat=%3Ccrossref_sprin%3E10_1007_s10870_010_9896_2%3C/crossref_sprin%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c288t-52321a16ac73a13bd3b764f37557a1dbb6854c7a8ea1efa93fd35bd9c7d283a53%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |