Loading…
Synthesis and Crystal Structure of Sodium Arsenate Oxyhydroxide: Na4(AsO4)OH
Single crystals of Na 4 (AsO 4 )OH were grown using the hydroflux method and characterized by single crystal X-ray diffraction. Na 4 (AsO 4 )OH crystallizes in the orthorhombic space group Pnma with a = 8.9467(11) Å, b = 7.3854(9) Å, and c = 8.2395(10) Å. The moisture sensitive material exhibits...
Saved in:
| Published in: | Journal of chemical crystallography 2015, Vol.45 (1), p.20-25 |
|---|---|
| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c2737-72c516f5f3e0ffb1bd064aaa8e21a90ed03ab0be66ba4fc53896135377def4d23 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c2737-72c516f5f3e0ffb1bd064aaa8e21a90ed03ab0be66ba4fc53896135377def4d23 |
| container_end_page | 25 |
| container_issue | 1 |
| container_start_page | 20 |
| container_title | Journal of chemical crystallography |
| container_volume | 45 |
| creator | zur Loye, Karl D. Latshaw, Allison M. Smith, Mark D. Chance, W. Michael zur Loye, Hans-Conrad |
| description | Single crystals of Na
4
(AsO
4
)OH were grown using the hydroflux method and characterized by single crystal X-ray diffraction. Na
4
(AsO
4
)OH crystallizes in the orthorhombic space group
Pnma
with
a
= 8.9467(11) Å,
b
= 7.3854(9) Å, and
c
= 8.2395(10) Å. The moisture sensitive material exhibits a three-dimensional crystal structure consisting of isolated AsO
4
3−
tetrahedra with the charge balance maintained by Na
+
and OH
−
. The asymmetric unit consists of one arsenic atom, three sodium atoms, four oxygen atoms, and one hydroxyl hydrogen atom. Arsenic, sodium, and oxygen atoms, as well as the hydroxyl hydrogen, are located on mirror planes; sodium is located on an inversion center.
Graphical Abstract
The synthesis and crystal structure are reported for Na
4
(AsO
4
)OH |
| doi_str_mv | 10.1007/s10870-014-0558-7 |
| format | article |
| fullrecord | <record><control><sourceid>crossref_sprin</sourceid><recordid>TN_cdi_crossref_primary_10_1007_s10870_014_0558_7</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1007_s10870_014_0558_7</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2737-72c516f5f3e0ffb1bd064aaa8e21a90ed03ab0be66ba4fc53896135377def4d23</originalsourceid><addsrcrecordid>eNp9kD1PwzAURS0EEqXwA9g8wmB4_oodtqiiFKkiQ2G2nNimqdoE2YnU_HtSlZnp3eGdq6uD0D2FJwqgnhMFrYAAFQSk1ERdoBmVihGtpbicMihBqBTsGt2ktAOAXDM1Q-vN2PZbn5qEbevwIo6pt3u86eNQ90P0uAt407lmOOAiJt_a3uPyOG5HF7tj4_wL_rDioUileCxXt-gq2H3yd393jr6Wr5-LFVmXb--LYk1qprgiitWSZkEG7iGEilYOMmGt1Z5Rm4N3wG0Flc-yyopQS67zjHLJlXI-CMf4HNFzbx27lKIP5ic2BxtHQ8GcdJizDjPpMCcdRk0MOzNp-m2_fTS7bojtNPMf6BdrjGKV</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis and Crystal Structure of Sodium Arsenate Oxyhydroxide: Na4(AsO4)OH</title><source>Springer Nature</source><creator>zur Loye, Karl D. ; Latshaw, Allison M. ; Smith, Mark D. ; Chance, W. Michael ; zur Loye, Hans-Conrad</creator><creatorcontrib>zur Loye, Karl D. ; Latshaw, Allison M. ; Smith, Mark D. ; Chance, W. Michael ; zur Loye, Hans-Conrad</creatorcontrib><description>Single crystals of Na
4
(AsO
4
)OH were grown using the hydroflux method and characterized by single crystal X-ray diffraction. Na
4
(AsO
4
)OH crystallizes in the orthorhombic space group
Pnma
with
a
= 8.9467(11) Å,
b
= 7.3854(9) Å, and
c
= 8.2395(10) Å. The moisture sensitive material exhibits a three-dimensional crystal structure consisting of isolated AsO
4
3−
tetrahedra with the charge balance maintained by Na
+
and OH
−
. The asymmetric unit consists of one arsenic atom, three sodium atoms, four oxygen atoms, and one hydroxyl hydrogen atom. Arsenic, sodium, and oxygen atoms, as well as the hydroxyl hydrogen, are located on mirror planes; sodium is located on an inversion center.
Graphical Abstract
The synthesis and crystal structure are reported for Na
4
(AsO
4
)OH</description><identifier>ISSN: 1074-1542</identifier><identifier>EISSN: 1572-8854</identifier><identifier>DOI: 10.1007/s10870-014-0558-7</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Chemistry ; Chemistry and Materials Science ; Crystallography and Scattering Methods ; Inorganic Chemistry ; Organometallic Chemistry ; Original Paper ; Physical Chemistry</subject><ispartof>Journal of chemical crystallography, 2015, Vol.45 (1), p.20-25</ispartof><rights>Springer Science+Business Media New York 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2737-72c516f5f3e0ffb1bd064aaa8e21a90ed03ab0be66ba4fc53896135377def4d23</citedby><cites>FETCH-LOGICAL-c2737-72c516f5f3e0ffb1bd064aaa8e21a90ed03ab0be66ba4fc53896135377def4d23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>zur Loye, Karl D.</creatorcontrib><creatorcontrib>Latshaw, Allison M.</creatorcontrib><creatorcontrib>Smith, Mark D.</creatorcontrib><creatorcontrib>Chance, W. Michael</creatorcontrib><creatorcontrib>zur Loye, Hans-Conrad</creatorcontrib><title>Synthesis and Crystal Structure of Sodium Arsenate Oxyhydroxide: Na4(AsO4)OH</title><title>Journal of chemical crystallography</title><addtitle>J Chem Crystallogr</addtitle><description>Single crystals of Na
4
(AsO
4
)OH were grown using the hydroflux method and characterized by single crystal X-ray diffraction. Na
4
(AsO
4
)OH crystallizes in the orthorhombic space group
Pnma
with
a
= 8.9467(11) Å,
b
= 7.3854(9) Å, and
c
= 8.2395(10) Å. The moisture sensitive material exhibits a three-dimensional crystal structure consisting of isolated AsO
4
3−
tetrahedra with the charge balance maintained by Na
+
and OH
−
. The asymmetric unit consists of one arsenic atom, three sodium atoms, four oxygen atoms, and one hydroxyl hydrogen atom. Arsenic, sodium, and oxygen atoms, as well as the hydroxyl hydrogen, are located on mirror planes; sodium is located on an inversion center.
Graphical Abstract
The synthesis and crystal structure are reported for Na
4
(AsO
4
)OH</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystallography and Scattering Methods</subject><subject>Inorganic Chemistry</subject><subject>Organometallic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><issn>1074-1542</issn><issn>1572-8854</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kD1PwzAURS0EEqXwA9g8wmB4_oodtqiiFKkiQ2G2nNimqdoE2YnU_HtSlZnp3eGdq6uD0D2FJwqgnhMFrYAAFQSk1ERdoBmVihGtpbicMihBqBTsGt2ktAOAXDM1Q-vN2PZbn5qEbevwIo6pt3u86eNQ90P0uAt407lmOOAiJt_a3uPyOG5HF7tj4_wL_rDioUileCxXt-gq2H3yd393jr6Wr5-LFVmXb--LYk1qprgiitWSZkEG7iGEilYOMmGt1Z5Rm4N3wG0Flc-yyopQS67zjHLJlXI-CMf4HNFzbx27lKIP5ic2BxtHQ8GcdJizDjPpMCcdRk0MOzNp-m2_fTS7bojtNPMf6BdrjGKV</recordid><startdate>2015</startdate><enddate>2015</enddate><creator>zur Loye, Karl D.</creator><creator>Latshaw, Allison M.</creator><creator>Smith, Mark D.</creator><creator>Chance, W. Michael</creator><creator>zur Loye, Hans-Conrad</creator><general>Springer US</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2015</creationdate><title>Synthesis and Crystal Structure of Sodium Arsenate Oxyhydroxide: Na4(AsO4)OH</title><author>zur Loye, Karl D. ; Latshaw, Allison M. ; Smith, Mark D. ; Chance, W. Michael ; zur Loye, Hans-Conrad</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2737-72c516f5f3e0ffb1bd064aaa8e21a90ed03ab0be66ba4fc53896135377def4d23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystallography and Scattering Methods</topic><topic>Inorganic Chemistry</topic><topic>Organometallic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>zur Loye, Karl D.</creatorcontrib><creatorcontrib>Latshaw, Allison M.</creatorcontrib><creatorcontrib>Smith, Mark D.</creatorcontrib><creatorcontrib>Chance, W. Michael</creatorcontrib><creatorcontrib>zur Loye, Hans-Conrad</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of chemical crystallography</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>zur Loye, Karl D.</au><au>Latshaw, Allison M.</au><au>Smith, Mark D.</au><au>Chance, W. Michael</au><au>zur Loye, Hans-Conrad</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Crystal Structure of Sodium Arsenate Oxyhydroxide: Na4(AsO4)OH</atitle><jtitle>Journal of chemical crystallography</jtitle><stitle>J Chem Crystallogr</stitle><date>2015</date><risdate>2015</risdate><volume>45</volume><issue>1</issue><spage>20</spage><epage>25</epage><pages>20-25</pages><issn>1074-1542</issn><eissn>1572-8854</eissn><abstract>Single crystals of Na
4
(AsO
4
)OH were grown using the hydroflux method and characterized by single crystal X-ray diffraction. Na
4
(AsO
4
)OH crystallizes in the orthorhombic space group
Pnma
with
a
= 8.9467(11) Å,
b
= 7.3854(9) Å, and
c
= 8.2395(10) Å. The moisture sensitive material exhibits a three-dimensional crystal structure consisting of isolated AsO
4
3−
tetrahedra with the charge balance maintained by Na
+
and OH
−
. The asymmetric unit consists of one arsenic atom, three sodium atoms, four oxygen atoms, and one hydroxyl hydrogen atom. Arsenic, sodium, and oxygen atoms, as well as the hydroxyl hydrogen, are located on mirror planes; sodium is located on an inversion center.
Graphical Abstract
The synthesis and crystal structure are reported for Na
4
(AsO
4
)OH</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10870-014-0558-7</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1074-1542 |
| ispartof | Journal of chemical crystallography, 2015, Vol.45 (1), p.20-25 |
| issn | 1074-1542 1572-8854 |
| language | eng |
| recordid | cdi_crossref_primary_10_1007_s10870_014_0558_7 |
| source | Springer Nature |
| subjects | Chemistry Chemistry and Materials Science Crystallography and Scattering Methods Inorganic Chemistry Organometallic Chemistry Original Paper Physical Chemistry |
| title | Synthesis and Crystal Structure of Sodium Arsenate Oxyhydroxide: Na4(AsO4)OH |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T20%3A17%3A49IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref_sprin&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20Crystal%20Structure%20of%20Sodium%20Arsenate%20Oxyhydroxide:%20Na4(AsO4)OH&rft.jtitle=Journal%20of%20chemical%20crystallography&rft.au=zur%20Loye,%20Karl%20D.&rft.date=2015&rft.volume=45&rft.issue=1&rft.spage=20&rft.epage=25&rft.pages=20-25&rft.issn=1074-1542&rft.eissn=1572-8854&rft_id=info:doi/10.1007/s10870-014-0558-7&rft_dat=%3Ccrossref_sprin%3E10_1007_s10870_014_0558_7%3C/crossref_sprin%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c2737-72c516f5f3e0ffb1bd064aaa8e21a90ed03ab0be66ba4fc53896135377def4d23%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |