Study of γ-irradiated Polymer Electrolyte for Zn Rechargeable Nanostructured Galvanic Cells by SAXS/DSC/WAXD method

(PEO) 8 ZnCl 2 polymer electrolytes and nanocomposites were prepared using PEO γ-irradiated with a dose of 529 kGy. The effect of γ-radiation from a Co-60 source were studied by small-angle X-ray scattering simultaneously recorded with differential scanning calorimetry and wide-angle X-ray diffracti...

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Bibliographic Details
Published in:Journal of inorganic and organometallic polymers and materials 2011-09, Vol.21 (3), p.706-710
Main Authors: Turković, A., Dubček, P., Juraić, K., Rakić, M., Bernstorff, S.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Communication
Inorganic Chemistry
Organic Chemistry
Polymer Sciences
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Summary:(PEO) 8 ZnCl 2 polymer electrolytes and nanocomposites were prepared using PEO γ-irradiated with a dose of 529 kGy. The effect of γ-radiation from a Co-60 source were studied by small-angle X-ray scattering simultaneously recorded with differential scanning calorimetry and wide-angle X-ray diffraction at the synchrotron ELETTRA. The abovementioned treatment largely enhanced the conductivity of the polymer electrolyte. A room temperature conductivity increase by up to two orders of magnitude was achieved by Turković et al. (J Electrochem Soc 154(6):A554, 2007 ).
ISSN:1574-1443
1574-1451
DOI:10.1007/s10904-011-9469-7