Crystal and molecular structure of [RuNO(NO2)4OHCuPyn] heterometallic complexes

Heterometallic complexes [RuNO(NO 2 ) 4 OHCuPy 2 (H 2 O)] ( I ) and [RuNO(NO 2 ) 4 OHCuPy 3 ] ( II ) are described structurally for the first time. In complex I , the ruthenium anion is coordinated to the copper atom by the bridging OH group and two bridging nitro groups; in complex II , by the brid...

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Bibliographic Details
Published in:Journal of structural chemistry 2010-06, Vol.51 (3), p.582-584
Main Authors: Kostin, G. A., Borodin, A. O., Kuratieva, N. V.
Format: Article
Language:English
Subjects:
Atomic
Atomic/Molecular Structure and Spectra
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Molecular
Optical and Plasma Physics
Physical Chemistry
Solid State Physics
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Summary:Heterometallic complexes [RuNO(NO 2 ) 4 OHCuPy 2 (H 2 O)] ( I ) and [RuNO(NO 2 ) 4 OHCuPy 3 ] ( II ) are described structurally for the first time. In complex I , the ruthenium anion is coordinated to the copper atom by the bridging OH group and two bridging nitro groups; in complex II , by the bridging OH group and one bridging nitro group. Dimers are formed in the crystal lattice of complex II due to the interaction of the copper atom and the nitro group of the ruthenium anion in trans position to the bridging NO 2 group.
ISSN:0022-4766
1573-8779
DOI:10.1007/s10947-010-0085-0