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Crystal Structure of (H3O)4[(C2H5)4N]6 [Th2Cl4(H2O)12O]3[Re4Se4(CN)12]4
Crystals of the rhenium cluster complex (H 3 O) 4 [(C 2 H 5 ) 4 N] 6 [Th 2 Cl 4 (H 2 O) 12 O] 3 [Re 4 Se 4 (CN) 12 ] 4 are obtained in an acidic (HCl) aqueous solution by the reaction of cluster salt K 4 [Re 4 Se 4 (CN) 12 ]·6H 2 O with ThCl 4 and (C 2 H 5 ) 4 NCl. Single crystal X-ray analysis show...
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Published in: | Journal of structural chemistry 2010, Vol.51 (4), p.782-784 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Crystals of the rhenium cluster complex (H
3
O)
4
[(C
2
H
5
)
4
N]
6
[Th
2
Cl
4
(H
2
O)
12
O]
3
[Re
4
Se
4
(CN)
12
]
4
are obtained in an acidic (HCl) aqueous solution by the reaction of cluster salt K
4
[Re
4
Se
4
(CN)
12
]·6H
2
O with ThCl
4
and (C
2
H
5
)
4
NCl. Single crystal X-ray analysis shows that the title compound is ionic and crystallizes in the cubic crystal system (
a
= 22.7322(3) Å,
V
= 11746.93(27) Å
3
,
Z
= 2,
I
4
3m
space group,
R
= 0.0350). It contains [Th
2
Cl
4
(H
2
O)
12
O]
2+
cations with two thorium atoms bonded to each other through the bridging oxygen atom forming an angle of 180° in the structure. |
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ISSN: | 0022-4766 1573-8779 |
DOI: | 10.1007/s10947-010-0117-9 |