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Crystal Structure of (H3O)4[(C2H5)4N]6 [Th2Cl4(H2O)12O]3[Re4Se4(CN)12]4
Crystals of the rhenium cluster complex (H 3 O) 4 [(C 2 H 5 ) 4 N] 6 [Th 2 Cl 4 (H 2 O) 12 O] 3 [Re 4 Se 4 (CN) 12 ] 4 are obtained in an acidic (HCl) aqueous solution by the reaction of cluster salt K 4 [Re 4 Se 4 (CN) 12 ]·6H 2 O with ThCl 4 and (C 2 H 5 ) 4 NCl. Single crystal X-ray analysis show...
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| Published in: | Journal of structural chemistry 2010, Vol.51 (4), p.782-784 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c2039-5132ae091d6c0b362d2c209a8b2db42d4d4f1accd11488054c230cbde65c91203 |
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| cites | cdi_FETCH-LOGICAL-c2039-5132ae091d6c0b362d2c209a8b2db42d4d4f1accd11488054c230cbde65c91203 |
| container_end_page | 784 |
| container_issue | 4 |
| container_start_page | 782 |
| container_title | Journal of structural chemistry |
| container_volume | 51 |
| creator | Efremova, O. A. Mironov, Yu. V. Kuratieva, N. V. Wang, K.-K. Fedorov, V. E. |
| description | Crystals of the rhenium cluster complex (H
3
O)
4
[(C
2
H
5
)
4
N]
6
[Th
2
Cl
4
(H
2
O)
12
O]
3
[Re
4
Se
4
(CN)
12
]
4
are obtained in an acidic (HCl) aqueous solution by the reaction of cluster salt K
4
[Re
4
Se
4
(CN)
12
]·6H
2
O with ThCl
4
and (C
2
H
5
)
4
NCl. Single crystal X-ray analysis shows that the title compound is ionic and crystallizes in the cubic crystal system (
a
= 22.7322(3) Å,
V
= 11746.93(27) Å
3
,
Z
= 2,
I
4
3m
space group,
R
= 0.0350). It contains [Th
2
Cl
4
(H
2
O)
12
O]
2+
cations with two thorium atoms bonded to each other through the bridging oxygen atom forming an angle of 180° in the structure. |
| doi_str_mv | 10.1007/s10947-010-0117-9 |
| format | article |
| fullrecord | <record><control><sourceid>crossref_sprin</sourceid><recordid>TN_cdi_crossref_primary_10_1007_s10947_010_0117_9</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1007_s10947_010_0117_9</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2039-5132ae091d6c0b362d2c209a8b2db42d4d4f1accd11488054c230cbde65c91203</originalsourceid><addsrcrecordid>eNp9kMFKAzEQhoMoWKsP4G2P20N0Jskmm6Ms2hVKF2w9lRJ2k6xaaivJ9tC3N6WePQzDMPP9DB8h9wgPCKAeI4IWigJCKlRUX5ARForTUil9SUYAjFGhpLwmNzFuAECXWo7ItArHOLTbbDGEgx0OwWf7Pstr3kzEKq9YXUzEfC2z1fKTVVuR16yZIGvWfPXmxcKLvJqneS1uyVXfbqO_--tj8v7yvKxqOmumr9XTjFoGXNMCOWs9aHTSQsclcywtdFt2zHWCOeFEj621DlGUJRTCMg62c14WVmOKGBM859qwjzH43vyEr-82HA2COZkwZxMmmTAnE0Ynhp2ZmG53Hz6Yzf4QdunNf6Bf7Rda0A</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Crystal Structure of (H3O)4[(C2H5)4N]6 [Th2Cl4(H2O)12O]3[Re4Se4(CN)12]4</title><source>Springer Link</source><creator>Efremova, O. A. ; Mironov, Yu. V. ; Kuratieva, N. V. ; Wang, K.-K. ; Fedorov, V. E.</creator><creatorcontrib>Efremova, O. A. ; Mironov, Yu. V. ; Kuratieva, N. V. ; Wang, K.-K. ; Fedorov, V. E.</creatorcontrib><description>Crystals of the rhenium cluster complex (H
3
O)
4
[(C
2
H
5
)
4
N]
6
[Th
2
Cl
4
(H
2
O)
12
O]
3
[Re
4
Se
4
(CN)
12
]
4
are obtained in an acidic (HCl) aqueous solution by the reaction of cluster salt K
4
[Re
4
Se
4
(CN)
12
]·6H
2
O with ThCl
4
and (C
2
H
5
)
4
NCl. Single crystal X-ray analysis shows that the title compound is ionic and crystallizes in the cubic crystal system (
a
= 22.7322(3) Å,
V
= 11746.93(27) Å
3
,
Z
= 2,
I
4
3m
space group,
R
= 0.0350). It contains [Th
2
Cl
4
(H
2
O)
12
O]
2+
cations with two thorium atoms bonded to each other through the bridging oxygen atom forming an angle of 180° in the structure.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1007/s10947-010-0117-9</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Solid State Physics</subject><ispartof>Journal of structural chemistry, 2010, Vol.51 (4), p.782-784</ispartof><rights>Pleiades Publishing, Ltd. 2010</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2039-5132ae091d6c0b362d2c209a8b2db42d4d4f1accd11488054c230cbde65c91203</citedby><cites>FETCH-LOGICAL-c2039-5132ae091d6c0b362d2c209a8b2db42d4d4f1accd11488054c230cbde65c91203</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids></links><search><creatorcontrib>Efremova, O. A.</creatorcontrib><creatorcontrib>Mironov, Yu. V.</creatorcontrib><creatorcontrib>Kuratieva, N. V.</creatorcontrib><creatorcontrib>Wang, K.-K.</creatorcontrib><creatorcontrib>Fedorov, V. E.</creatorcontrib><title>Crystal Structure of (H3O)4[(C2H5)4N]6 [Th2Cl4(H2O)12O]3[Re4Se4(CN)12]4</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>Crystals of the rhenium cluster complex (H
3
O)
4
[(C
2
H
5
)
4
N]
6
[Th
2
Cl
4
(H
2
O)
12
O]
3
[Re
4
Se
4
(CN)
12
]
4
are obtained in an acidic (HCl) aqueous solution by the reaction of cluster salt K
4
[Re
4
Se
4
(CN)
12
]·6H
2
O with ThCl
4
and (C
2
H
5
)
4
NCl. Single crystal X-ray analysis shows that the title compound is ionic and crystallizes in the cubic crystal system (
a
= 22.7322(3) Å,
V
= 11746.93(27) Å
3
,
Z
= 2,
I
4
3m
space group,
R
= 0.0350). It contains [Th
2
Cl
4
(H
2
O)
12
O]
2+
cations with two thorium atoms bonded to each other through the bridging oxygen atom forming an angle of 180° in the structure.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Solid State Physics</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp9kMFKAzEQhoMoWKsP4G2P20N0Jskmm6Ms2hVKF2w9lRJ2k6xaaivJ9tC3N6WePQzDMPP9DB8h9wgPCKAeI4IWigJCKlRUX5ARForTUil9SUYAjFGhpLwmNzFuAECXWo7ItArHOLTbbDGEgx0OwWf7Pstr3kzEKq9YXUzEfC2z1fKTVVuR16yZIGvWfPXmxcKLvJqneS1uyVXfbqO_--tj8v7yvKxqOmumr9XTjFoGXNMCOWs9aHTSQsclcywtdFt2zHWCOeFEj621DlGUJRTCMg62c14WVmOKGBM859qwjzH43vyEr-82HA2COZkwZxMmmTAnE0Ynhp2ZmG53Hz6Yzf4QdunNf6Bf7Rda0A</recordid><startdate>2010</startdate><enddate>2010</enddate><creator>Efremova, O. A.</creator><creator>Mironov, Yu. V.</creator><creator>Kuratieva, N. V.</creator><creator>Wang, K.-K.</creator><creator>Fedorov, V. E.</creator><general>Springer US</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2010</creationdate><title>Crystal Structure of (H3O)4[(C2H5)4N]6 [Th2Cl4(H2O)12O]3[Re4Se4(CN)12]4</title><author>Efremova, O. A. ; Mironov, Yu. V. ; Kuratieva, N. V. ; Wang, K.-K. ; Fedorov, V. E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2039-5132ae091d6c0b362d2c209a8b2db42d4d4f1accd11488054c230cbde65c91203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Solid State Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Efremova, O. A.</creatorcontrib><creatorcontrib>Mironov, Yu. V.</creatorcontrib><creatorcontrib>Kuratieva, N. V.</creatorcontrib><creatorcontrib>Wang, K.-K.</creatorcontrib><creatorcontrib>Fedorov, V. E.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Efremova, O. A.</au><au>Mironov, Yu. V.</au><au>Kuratieva, N. V.</au><au>Wang, K.-K.</au><au>Fedorov, V. E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal Structure of (H3O)4[(C2H5)4N]6 [Th2Cl4(H2O)12O]3[Re4Se4(CN)12]4</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2010</date><risdate>2010</risdate><volume>51</volume><issue>4</issue><spage>782</spage><epage>784</epage><pages>782-784</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>Crystals of the rhenium cluster complex (H
3
O)
4
[(C
2
H
5
)
4
N]
6
[Th
2
Cl
4
(H
2
O)
12
O]
3
[Re
4
Se
4
(CN)
12
]
4
are obtained in an acidic (HCl) aqueous solution by the reaction of cluster salt K
4
[Re
4
Se
4
(CN)
12
]·6H
2
O with ThCl
4
and (C
2
H
5
)
4
NCl. Single crystal X-ray analysis shows that the title compound is ionic and crystallizes in the cubic crystal system (
a
= 22.7322(3) Å,
V
= 11746.93(27) Å
3
,
Z
= 2,
I
4
3m
space group,
R
= 0.0350). It contains [Th
2
Cl
4
(H
2
O)
12
O]
2+
cations with two thorium atoms bonded to each other through the bridging oxygen atom forming an angle of 180° in the structure.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10947-010-0117-9</doi><tpages>3</tpages></addata></record> |
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| ispartof | Journal of structural chemistry, 2010, Vol.51 (4), p.782-784 |
| issn | 0022-4766 1573-8779 |
| language | eng |
| recordid | cdi_crossref_primary_10_1007_s10947_010_0117_9 |
| source | Springer Link |
| subjects | Atomic Atomic/Molecular Structure and Spectra Chemistry Chemistry and Materials Science Inorganic Chemistry Molecular Optical and Plasma Physics Physical Chemistry Solid State Physics |
| title | Crystal Structure of (H3O)4[(C2H5)4N]6 [Th2Cl4(H2O)12O]3[Re4Se4(CN)12]4 |
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