Catalytic oxidation of fatty acids. II. Epoxidation and oxidative cleavage of unsaturated fatty acid esters containing additional functional groups

Methyl esters of monounsaturated fatty acids were oxidized with aqueous hydrogen peroxide in biphasic organic-aqueous systems in the presence of catalyst [Me( n -C 8 H 17 ) 3 N] 3 {PO 4 [WO(O 2 ) 2 ] 4 }. Epoxidation and oxidative cleavage of the C=C bond were found to proceed with high conversion a...

Full description

Saved in:
Bibliographic Details
Published in:Reaction kinetics and catalysis letters 2009-10, Vol.98 (1), p.9-17
Main Authors: Khlebnikova, Tatiana B., Pai, Zinaida P., Fedoseeva, Larisa A., Mattsat, Yulia V.
Format: Article
Language:English
Subjects:
Catalysis
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
Physical Chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Methyl esters of monounsaturated fatty acids were oxidized with aqueous hydrogen peroxide in biphasic organic-aqueous systems in the presence of catalyst [Me( n -C 8 H 17 ) 3 N] 3 {PO 4 [WO(O 2 ) 2 ] 4 }. Epoxidation and oxidative cleavage of the C=C bond were found to proceed with high conversion and selectivity in the absence of organic solvents and under rather mild conditions ( T  
ISSN:0133-1736
1588-2837
DOI:10.1007/s11144-009-0054-9