Catalytic oxidation of fatty acids. I. Epoxidation of unsaturated fatty acids

Unsaturated fatty acids and their derivatives were oxidized with aqueous hydrogen peroxide in two-phase systems in the presence of homogeneous catalysts Q 3 {PO 4 [WO(O 2 ) 2 ] 4 }, where Q is [Bu 4 n ] 3 + , [C 5 H 5 N( n -C 16 H 33 )] 3 + or [Me( n -C 8 H 17 ) 3 N] 3 + . The reactions occurred und...

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Bibliographic Details
Published in:Reaction kinetics and catalysis letters 2009-10, Vol.98 (1), p.1-8
Main Authors: Pai, Zinaida P., Khlebnikova, Tatiana B., Mattsat, Yulia V., Parmon, Valentin N.
Format: Article
Language:English
Subjects:
Catalysis
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
Physical Chemistry
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Summary:Unsaturated fatty acids and their derivatives were oxidized with aqueous hydrogen peroxide in two-phase systems in the presence of homogeneous catalysts Q 3 {PO 4 [WO(O 2 ) 2 ] 4 }, where Q is [Bu 4 n ] 3 + , [C 5 H 5 N( n -C 16 H 33 )] 3 + or [Me( n -C 8 H 17 ) 3 N] 3 + . The reactions occurred under mild conditions ( T  
ISSN:0133-1736
1588-2837
DOI:10.1007/s11144-009-0069-2