Synthesis of a cellulose xanthate supported palladium(0) complex and its catalytic behavior in the Heck reaction

A cellulose xanthate supported palladium(0) complex was synthesized using a simple method and characterized by XPS, TG/DTA etc. The complex has good thermal stability from room temperature to 250 °C and it was found to be an efficient catalyst for the Heck reaction of acrylic acid or styrene with ar...

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Bibliographic Details
Published in:Reaction Kinetics, Mechanisms and Catalysis Mechanisms and Catalysis, 2010-08, Vol.100 (2), p.347-353
Main Authors: Xu, Ying, Xue, Man, Li, Jinjin, Zhang, Liujie, Cui, Yuanchen
Format: Article
Language:English
Subjects:
Catalysis
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
Physical Chemistry
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Summary:A cellulose xanthate supported palladium(0) complex was synthesized using a simple method and characterized by XPS, TG/DTA etc. The complex has good thermal stability from room temperature to 250 °C and it was found to be an efficient catalyst for the Heck reaction of acrylic acid or styrene with aryl iodide at low temperature under atmospheric pressure, and the substituted trans -cinnamic acid or 1, 2-stilbene was obtained with high yield at 90 °C. The reaction duration is about 8 h. The cellulose xanthate supported palladium(0) complex could be separated from the reaction mixture easily and reused for several cycles. The yield of the product was up to 55.3% when the catalyst was run for 10 times. The active center in the complex is Pd metal.
ISSN:1878-5190
1588-2837
1878-5204
DOI:10.1007/s11144-010-0191-1