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[(C18H37)2(CH3)2N]7[PW11O39]: a temperature-controlled phase transfer catalyst for olefin epoxidation
A novel temperature-controlled phase transfer catalytic system based on [(C 18 H 37 ) 2 (CH 3 ) 2 N] 7 [PW 11 O 39 ] for olefin epoxidation was demonstrated. The reaction was conducted in a non-chlorinated solvent of ethyl acetate with hydrogen peroxide. The catalyst was easily recovered and reused...
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| Published in: | Reaction kinetics, mechanisms and catalysis mechanisms and catalysis, 2011-02, Vol.102 (1), p.93-102 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c2037-218f705421cb3745bc3315d4ba496d4ba7ab781e09f0918ccd0380de6d0e6c333 |
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| cites | cdi_FETCH-LOGICAL-c2037-218f705421cb3745bc3315d4ba496d4ba7ab781e09f0918ccd0380de6d0e6c333 |
| container_end_page | 102 |
| container_issue | 1 |
| container_start_page | 93 |
| container_title | Reaction kinetics, mechanisms and catalysis |
| container_volume | 102 |
| creator | Zhao, Wei Ding, Yong Zhang, Zhenxin Ma, Baochun Qiu, Wenyuan |
| description | A novel temperature-controlled phase transfer catalytic system based on [(C
18
H
37
)
2
(CH
3
)
2
N]
7
[PW
11
O
39
] for olefin epoxidation was demonstrated. The reaction was conducted in a non-chlorinated solvent of ethyl acetate with hydrogen peroxide. The catalyst was easily recovered and reused even ten cycles without loss in activity and selectivity. |
| doi_str_mv | 10.1007/s11144-010-0242-7 |
| format | article |
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H
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(CH
3
)
2
N]
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18
H
37
)
2
(CH
3
)
2
N]
7
[PW
11
O
39
] for olefin epoxidation was demonstrated. The reaction was conducted in a non-chlorinated solvent of ethyl acetate with hydrogen peroxide. The catalyst was easily recovered and reused even ten cycles without loss in activity and selectivity.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11144-010-0242-7</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1878-5190 |
| ispartof | Reaction kinetics, mechanisms and catalysis, 2011-02, Vol.102 (1), p.93-102 |
| issn | 1878-5190 1878-5204 |
| language | eng |
| recordid | cdi_crossref_primary_10_1007_s11144_010_0242_7 |
| source | Springer Nature:Jisc Collections:Springer Nature Read and Publish 2023-2025: Springer Reading List |
| subjects | Catalysis Chemistry Chemistry and Materials Science Industrial Chemistry/Chemical Engineering Physical Chemistry |
| title | [(C18H37)2(CH3)2N]7[PW11O39]: a temperature-controlled phase transfer catalyst for olefin epoxidation |
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