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Redox reaction of nitric oxide and carbon monoxide over Fe2O3 and Co3O4 phases
Fe 2 O 3 and Co 3 O 4 phases are synthesized by the thermal treatment in an air-flow of hydrated salts based on Fe and Co. The materials are characterized by X-ray diffraction, energy dispersive spectroscopy, scanning electron microscopy, thermogravimetric analysis and surface area measurements. Fe...
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| Published in: | Reaction kinetics, mechanisms and catalysis mechanisms and catalysis, 2016-04, Vol.117 (2), p.593-604 |
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| cited_by | cdi_FETCH-LOGICAL-c395t-c3f5c06a1045fa4e2e1307dc7aa5e93fcc2681c3725946e2a3e98a259bf8c8373 |
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| cites | cdi_FETCH-LOGICAL-c395t-c3f5c06a1045fa4e2e1307dc7aa5e93fcc2681c3725946e2a3e98a259bf8c8373 |
| container_end_page | 604 |
| container_issue | 2 |
| container_start_page | 593 |
| container_title | Reaction kinetics, mechanisms and catalysis |
| container_volume | 117 |
| creator | Flores-Sanchez, L. A. Quintana-Melgoza, J. M. Valdez, R. Olivas, A. Avalos-Borja, M. |
| description | Fe
2
O
3
and Co
3
O
4
phases are synthesized by the thermal treatment in an air-flow of hydrated salts based on Fe and Co. The materials are characterized by X-ray diffraction, energy dispersive spectroscopy, scanning electron microscopy, thermogravimetric analysis and surface area measurements. Fe
2
O
3
and Co
3
O
4
were tested for nitric oxide reduction with carbon monoxide in a 1:5 gas phase ratio and showed reaction rates in a range from 8.7 × 10
−11
to 5.9 × 10
−10
mol s
−1
g
−1
with an activation energy interval from 50.2 to 54.4 kJ mol
−1
. Fe
2
O
3
and Co
3
O
4
achieved (100 and 98) % NO conversion with (96 and 80) % selectivity to N
2
at (275 and 350) °C. Fe
2
O
3
and Co
3
O
4
have the advantages such as facile synthesis, low-cost, good thermal stability, high activity and selective to N
2
. These results regarding activity and selectivity are better or similar to some catalysts based on noble metals (Rh, Pt and Pd) currently used for air pollutants control. |
| doi_str_mv | 10.1007/s11144-015-0962-9 |
| format | article |
| fullrecord | <record><control><sourceid>crossref_sprin</sourceid><recordid>TN_cdi_crossref_primary_10_1007_s11144_015_0962_9</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1007_s11144_015_0962_9</sourcerecordid><originalsourceid>FETCH-LOGICAL-c395t-c3f5c06a1045fa4e2e1307dc7aa5e93fcc2681c3725946e2a3e98a259bf8c8373</originalsourceid><addsrcrecordid>eNp9kM1KAzEQx4MoWGofwFteYDWTj01ylGJVKBZEzyHNTnSL3ZSkSn17U1evzmG-_8PwI-QS2BUwpq8LAEjZMFANsy1v7AmZgNGmUZzJ078cLDsns1I2rJrg2ig7IY9P2KUDzejDvk8DTZEO_T73gaZD3yH1Q0eDz-s62qZh7KVPzHSBfCV-xvMkVpLu3nzBckHOon8vOPuNU_KyuH2e3zfL1d3D_GbZBGHVvvqoAms9MKmil8gRBNNd0N4rtCKGwFsDQWiurGyRe4HW-FqsowlGaDElMN4NOZWSMbpd7rc-fzlg7sjEjUxcZeKOTJytGj5qSt0dXjG7TfrIQ33zH9E3YBJi6g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Redox reaction of nitric oxide and carbon monoxide over Fe2O3 and Co3O4 phases</title><source>Springer Nature</source><creator>Flores-Sanchez, L. A. ; Quintana-Melgoza, J. M. ; Valdez, R. ; Olivas, A. ; Avalos-Borja, M.</creator><creatorcontrib>Flores-Sanchez, L. A. ; Quintana-Melgoza, J. M. ; Valdez, R. ; Olivas, A. ; Avalos-Borja, M.</creatorcontrib><description>Fe
2
O
3
and Co
3
O
4
phases are synthesized by the thermal treatment in an air-flow of hydrated salts based on Fe and Co. The materials are characterized by X-ray diffraction, energy dispersive spectroscopy, scanning electron microscopy, thermogravimetric analysis and surface area measurements. Fe
2
O
3
and Co
3
O
4
were tested for nitric oxide reduction with carbon monoxide in a 1:5 gas phase ratio and showed reaction rates in a range from 8.7 × 10
−11
to 5.9 × 10
−10
mol s
−1
g
−1
with an activation energy interval from 50.2 to 54.4 kJ mol
−1
. Fe
2
O
3
and Co
3
O
4
achieved (100 and 98) % NO conversion with (96 and 80) % selectivity to N
2
at (275 and 350) °C. Fe
2
O
3
and Co
3
O
4
have the advantages such as facile synthesis, low-cost, good thermal stability, high activity and selective to N
2
. These results regarding activity and selectivity are better or similar to some catalysts based on noble metals (Rh, Pt and Pd) currently used for air pollutants control.</description><identifier>ISSN: 1878-5190</identifier><identifier>EISSN: 1878-5204</identifier><identifier>DOI: 10.1007/s11144-015-0962-9</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Catalysis ; Chemistry ; Chemistry and Materials Science ; Industrial Chemistry/Chemical Engineering ; Physical Chemistry</subject><ispartof>Reaction kinetics, mechanisms and catalysis, 2016-04, Vol.117 (2), p.593-604</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c395t-c3f5c06a1045fa4e2e1307dc7aa5e93fcc2681c3725946e2a3e98a259bf8c8373</citedby><cites>FETCH-LOGICAL-c395t-c3f5c06a1045fa4e2e1307dc7aa5e93fcc2681c3725946e2a3e98a259bf8c8373</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Flores-Sanchez, L. A.</creatorcontrib><creatorcontrib>Quintana-Melgoza, J. M.</creatorcontrib><creatorcontrib>Valdez, R.</creatorcontrib><creatorcontrib>Olivas, A.</creatorcontrib><creatorcontrib>Avalos-Borja, M.</creatorcontrib><title>Redox reaction of nitric oxide and carbon monoxide over Fe2O3 and Co3O4 phases</title><title>Reaction kinetics, mechanisms and catalysis</title><addtitle>Reac Kinet Mech Cat</addtitle><description>Fe
2
O
3
and Co
3
O
4
phases are synthesized by the thermal treatment in an air-flow of hydrated salts based on Fe and Co. The materials are characterized by X-ray diffraction, energy dispersive spectroscopy, scanning electron microscopy, thermogravimetric analysis and surface area measurements. Fe
2
O
3
and Co
3
O
4
were tested for nitric oxide reduction with carbon monoxide in a 1:5 gas phase ratio and showed reaction rates in a range from 8.7 × 10
−11
to 5.9 × 10
−10
mol s
−1
g
−1
with an activation energy interval from 50.2 to 54.4 kJ mol
−1
. Fe
2
O
3
and Co
3
O
4
achieved (100 and 98) % NO conversion with (96 and 80) % selectivity to N
2
at (275 and 350) °C. Fe
2
O
3
and Co
3
O
4
have the advantages such as facile synthesis, low-cost, good thermal stability, high activity and selective to N
2
. These results regarding activity and selectivity are better or similar to some catalysts based on noble metals (Rh, Pt and Pd) currently used for air pollutants control.</description><subject>Catalysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Physical Chemistry</subject><issn>1878-5190</issn><issn>1878-5204</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kM1KAzEQx4MoWGofwFteYDWTj01ylGJVKBZEzyHNTnSL3ZSkSn17U1evzmG-_8PwI-QS2BUwpq8LAEjZMFANsy1v7AmZgNGmUZzJ078cLDsns1I2rJrg2ig7IY9P2KUDzejDvk8DTZEO_T73gaZD3yH1Q0eDz-s62qZh7KVPzHSBfCV-xvMkVpLu3nzBckHOon8vOPuNU_KyuH2e3zfL1d3D_GbZBGHVvvqoAms9MKmil8gRBNNd0N4rtCKGwFsDQWiurGyRe4HW-FqsowlGaDElMN4NOZWSMbpd7rc-fzlg7sjEjUxcZeKOTJytGj5qSt0dXjG7TfrIQ33zH9E3YBJi6g</recordid><startdate>20160401</startdate><enddate>20160401</enddate><creator>Flores-Sanchez, L. A.</creator><creator>Quintana-Melgoza, J. M.</creator><creator>Valdez, R.</creator><creator>Olivas, A.</creator><creator>Avalos-Borja, M.</creator><general>Springer Netherlands</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20160401</creationdate><title>Redox reaction of nitric oxide and carbon monoxide over Fe2O3 and Co3O4 phases</title><author>Flores-Sanchez, L. A. ; Quintana-Melgoza, J. M. ; Valdez, R. ; Olivas, A. ; Avalos-Borja, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c395t-c3f5c06a1045fa4e2e1307dc7aa5e93fcc2681c3725946e2a3e98a259bf8c8373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Catalysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Flores-Sanchez, L. A.</creatorcontrib><creatorcontrib>Quintana-Melgoza, J. M.</creatorcontrib><creatorcontrib>Valdez, R.</creatorcontrib><creatorcontrib>Olivas, A.</creatorcontrib><creatorcontrib>Avalos-Borja, M.</creatorcontrib><collection>CrossRef</collection><jtitle>Reaction kinetics, mechanisms and catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Flores-Sanchez, L. A.</au><au>Quintana-Melgoza, J. M.</au><au>Valdez, R.</au><au>Olivas, A.</au><au>Avalos-Borja, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Redox reaction of nitric oxide and carbon monoxide over Fe2O3 and Co3O4 phases</atitle><jtitle>Reaction kinetics, mechanisms and catalysis</jtitle><stitle>Reac Kinet Mech Cat</stitle><date>2016-04-01</date><risdate>2016</risdate><volume>117</volume><issue>2</issue><spage>593</spage><epage>604</epage><pages>593-604</pages><issn>1878-5190</issn><eissn>1878-5204</eissn><abstract>Fe
2
O
3
and Co
3
O
4
phases are synthesized by the thermal treatment in an air-flow of hydrated salts based on Fe and Co. The materials are characterized by X-ray diffraction, energy dispersive spectroscopy, scanning electron microscopy, thermogravimetric analysis and surface area measurements. Fe
2
O
3
and Co
3
O
4
were tested for nitric oxide reduction with carbon monoxide in a 1:5 gas phase ratio and showed reaction rates in a range from 8.7 × 10
−11
to 5.9 × 10
−10
mol s
−1
g
−1
with an activation energy interval from 50.2 to 54.4 kJ mol
−1
. Fe
2
O
3
and Co
3
O
4
achieved (100 and 98) % NO conversion with (96 and 80) % selectivity to N
2
at (275 and 350) °C. Fe
2
O
3
and Co
3
O
4
have the advantages such as facile synthesis, low-cost, good thermal stability, high activity and selective to N
2
. These results regarding activity and selectivity are better or similar to some catalysts based on noble metals (Rh, Pt and Pd) currently used for air pollutants control.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11144-015-0962-9</doi><tpages>12</tpages></addata></record> |
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| ispartof | Reaction kinetics, mechanisms and catalysis, 2016-04, Vol.117 (2), p.593-604 |
| issn | 1878-5190 1878-5204 |
| language | eng |
| recordid | cdi_crossref_primary_10_1007_s11144_015_0962_9 |
| source | Springer Nature |
| subjects | Catalysis Chemistry Chemistry and Materials Science Industrial Chemistry/Chemical Engineering Physical Chemistry |
| title | Redox reaction of nitric oxide and carbon monoxide over Fe2O3 and Co3O4 phases |
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