Catalytic activity of vanadium oxide catalysts prepared by electrodeposition for the selective catalytic reduction of nitrogen oxides with ammonia

• Published in: Reaction kinetics, mechanisms and catalysis mechanisms and catalysis, 2016-08, Vol.118 (2), p.633-641
• Main Authors: Kim, Su Hyo, Cha, Jin Sun, Jeon, Yoo Sang, Park, Bum Chul, Shin, Min-Chul, Song, Jun-Kwang, Kim, Young Keun
• Format: Article
• Language: English
• Subjects: Catalysis; Chemistry; Chemistry and Materials Science; Industrial Chemistry/Chemical Engineering; Physical Chemistry
• ISSN: 1878-5190; 1878-5204
• DOI: 10.1007/s11144-016-1010-0

A facile synthesis of nanostructured vanadium oxide catalysts grown inside a honeycomb ceramic filter by electrodeposition without heat treatment is reported. The prepared catalysts are investigated for a selective catalytic reduction (SCR) of nitrogen oxide (NO x ) with ammonia (NH 3 ) in the temperature ranges from 250 to 450 °C. The SCR test results indicate that the NO x removal efficiency of the as-deposited sample is comparable to that of the sample heat treated at 600 °C as well as that of the sample prepared by conventional wash coating method. The nanostructured catalysts show similar NO x removal efficiencies after several recycles. Both polycrystalline and amorphous phases co-exist in the electrodeposited V-oxide catalysts confirmed by X-ray diffraction and selective area electron diffraction. The V-oxide catalysts show stronger V=O bond peaks and higher ratio of V 4+ /V 5+ and O α /O β on their surfaces as characterized by Raman spectroscopy and X-ray photoelectron spectroscopy.