Studies of porphyrin zinc compounds intercalated into V2O5 xerogel

The intercalation of meso -tetrakis(4-pyridyl)porphyrin zinc, the cationic salts of meso -tetrakis( N -methylpyridinium-4-yl)porphyrin zinc, and zwitterionic meso -tetrakis-[ N -(3-sulfonatopropyl)pyridinium-4-yl]porphyrin zinc from aqueous solutions as well as of meso -tetrakis( N -methylpyricliniu...

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Bibliographic Details
Published in:Russian chemical bulletin 2009-11, Vol.58 (11), p.2233-2239
Main Authors: Suvorova, O. N., Domrachev, G. A., Shchupak, E. A., Kudryavtseva, G. S., Kirillov, A. I., Zaitsev, A. A.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Inorganic Chemistry
Organic Chemistry
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Summary:The intercalation of meso -tetrakis(4-pyridyl)porphyrin zinc, the cationic salts of meso -tetrakis( N -methylpyridinium-4-yl)porphyrin zinc, and zwitterionic meso -tetrakis-[ N -(3-sulfonatopropyl)pyridinium-4-yl]porphyrin zinc from aqueous solutions as well as of meso -tetrakis( N -methylpyriclinium-4-yl)porphyrin zinc from pyridine solutions into V 2 O 5 xerogel was studied. The intercalation complexes obtained were characterized by X-ray diffraction analysis, TG analysis, IR, and UV reflectance spectroscopy.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-009-0311-0