First optically active P-alkoxy derivative of palladated phosphacymantrene: synthesis, structure, and chiroptical properties

The solvopalladation reaction of 2,5-diphenylphosphacymantrene with Na 2 PdCl 4 , AcONa, and optically active carbinol ( S )-(−)-2-methylbutanol was carried out. Optically active complex 3 was obtained and characterized by X-ray diffraction analysis and circular dichroism (CD), 13 C and 31 P NMR, IR...

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Bibliographic Details
Published in:Russian chemical bulletin 2013-04, Vol.62 (4), p.1080-1085
Main Authors: Smol’yakov, A. F., Ginzburg, A. G., Bashilov, V. V., Dolgushin, F. M., Petrovskii, P. V., Babievsky, K. K., Sokolov, V. I.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Inorganic Chemistry
Organic Chemistry
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Summary:The solvopalladation reaction of 2,5-diphenylphosphacymantrene with Na 2 PdCl 4 , AcONa, and optically active carbinol ( S )-(−)-2-methylbutanol was carried out. Optically active complex 3 was obtained and characterized by X-ray diffraction analysis and circular dichroism (CD), 13 C and 31 P NMR, IR, and UV spectra.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-013-0145-7