Binuclear terbium(iii) pivalates with 4,7-diphenyl-1,10-phenanthroline: synthesis, structure, thermal decomposition, and magnetic and luminescence properties

New binuclear pivalate complexes (bath) 2 Tb 2 (piv) 6 and (bath) 2 Tb 2 (piv) 6 ·H 2 O (piv = = Bu t CCO 2 − , bath is 4,7-diphenyl-1,10-phenanthroline) were synthesized. The thermal behavior of these complexes was studied by differential scanning calorimetry and thermogravimetric analysis. The com...

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Published in:Russian chemical bulletin 2014-04, Vol.63 (4), p.938-944
Main Authors: Fomina, I. G., Dobrokhotova, Zh. V., Ilyukhin, A. B., Aleksandrov, G. G., Gavrikov, A. V., Bogomyakov, A. S., Gekhman, A. E., Zavorotnyi, Yu. S., Gerasimova, V. I., Novotortsev, V. M., Eremenko, I. L.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Inorganic Chemistry
Organic Chemistry
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Summary:New binuclear pivalate complexes (bath) 2 Tb 2 (piv) 6 and (bath) 2 Tb 2 (piv) 6 ·H 2 O (piv = = Bu t CCO 2 − , bath is 4,7-diphenyl-1,10-phenanthroline) were synthesized. The thermal behavior of these complexes was studied by differential scanning calorimetry and thermogravimetric analysis. The composition of the complexes in the gas phase was determined, and their magnetic and photoluminescence properties were studied. The structures of the compounds (bath) 2 Tb 2 (piv) 6 and (bath) 2 Tb 2 (piv) 6 ·H 2 O were determined by X-ray diffraction.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-014-0531-9