Novel catalysts for selective hydrogenation of C≡C bond based on Pd nanoparticles immobilized in phenylenecarboxylate frameworks (NH2)-MIL-53(Al)

Novel catalysts based on Pd nanoparticles encapsulated into microporous metal-organic framework MIL-53(Al) and NH 2 -MIL-53(Al) were synthesized. Their catalytic properties were studied in the model reaction of liquid-phase hydrogenation of diphenylacetylene (DPA) (293 K, = 5 atm). The activity and...

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Bibliographic Details
Published in:Russian chemical bulletin 2015-02, Vol.64 (2), p.284-290
Main Authors: Stakheev, A. Yu, Isaeva, V. I., Markov, P. V., Turova, O. V., Mashkovskii, I. S., Kapustin, G. I., Saifutdinov, B. R., Kustov, L. M.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Inorganic Chemistry
Organic Chemistry
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Summary:Novel catalysts based on Pd nanoparticles encapsulated into microporous metal-organic framework MIL-53(Al) and NH 2 -MIL-53(Al) were synthesized. Their catalytic properties were studied in the model reaction of liquid-phase hydrogenation of diphenylacetylene (DPA) (293 K, = 5 atm). The activity and selectively of the palladium-containing materials Pd—MIL in DPA hydrogenation depend substantially on the nature of the organic linker.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-015-0858-x