Five-membered cyclic nitroxyl radicals as inhibitors of the oxidation of methyl linoleate in micelles

The kinetics of methyl linoleate oxidation in micelles inhibited by five-membered cyclic nitroxyl radicals and the corresponding hydroxylamines was studied. The partial regeneration of nitroxyl radicals in this process was found. The activity of the studied inhibitors increases with an increase in t...

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Bibliographic Details
Published in:Russian chemical bulletin 2015-12, Vol.64 (12), p.2869-2871
Main Authors: Tikhonov, I. V., Pliss, E. M., Borodin, L. I., Sen´, V. D.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Inorganic Chemistry
Organic Chemistry
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Summary:The kinetics of methyl linoleate oxidation in micelles inhibited by five-membered cyclic nitroxyl radicals and the corresponding hydroxylamines was studied. The partial regeneration of nitroxyl radicals in this process was found. The activity of the studied inhibitors increases with an increase in their lipophilicity.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-015-1240-8