Alkylation of catechol with cyclohexene. Novel sterically hindered o-quinones and catechols

A synthetic procedure for the preparation of sterically hindered catechols and o -quinones by the reaction of catechol with cyclohexene was developed. Novel cyclohexyl substituted catechols displayed remarkable stability during redox transformations and could be used as redoxactive ligands.

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Bibliographic Details
Published in:Russian chemical bulletin 2020-12, Vol.69 (12), p.2383-2389
Main Authors: Kocherova, T. N., Druzhkov, N. O., Martyanov, K. A., Shavyrin, A. S., Arsenyev, M. V., Kulikova, T. I., Baranov, E. V., Kuropatov, V. A., Cherkasov, V. K.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Inorganic Chemistry
Organic Chemistry
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Summary:A synthetic procedure for the preparation of sterically hindered catechols and o -quinones by the reaction of catechol with cyclohexene was developed. Novel cyclohexyl substituted catechols displayed remarkable stability during redox transformations and could be used as redoxactive ligands.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-020-3051-9