Unexpected 3:2 stoichiometry and structure of 15-crown-5 complex with lithium chlorochromate

X-ray diffraction study of the lithium chlorochromate complex with 15-crown-5 (15C5) revealed the existence of an unexpected complex dication with [(15C5) 3 Li 2 (H 2 O) 2 ] 2+ composition, which is also stable in the gas phase according to the quantum-chemical calculations by B3LYP/6-311+G(d,p) met...

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Bibliographic Details
Published in:Structural chemistry 2009-02, Vol.20 (1), p.139-143
Main Authors: Shishkin, Oleg V., Zubatyuk, Roman I., Zhovtyak, Oleg Yu, Kiriyak, Andrey V., Kotlyar, Sergei A., Kamalov, Gerbert L.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Computer Applications in Chemistry
Original Research
Physical Chemistry
Theoretical and Computational Chemistry
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Summary:X-ray diffraction study of the lithium chlorochromate complex with 15-crown-5 (15C5) revealed the existence of an unexpected complex dication with [(15C5) 3 Li 2 (H 2 O) 2 ] 2+ composition, which is also stable in the gas phase according to the quantum-chemical calculations by B3LYP/6-311+G(d,p) method.
ISSN:1040-0400
1572-9001
DOI:10.1007/s11224-008-9388-6