Effect of the Redox Properties of the Zinc and Nickel Metal–Organic Frameworks on Peculiarities of Their Interaction with Iodine and the Electronic Conductivity of the Composites Formed

The kinetics of the adsorption and desorption of iodine from solution by isostructural metal–organic frameworks formed by macrocyclic nickel or zinc cations and 4,4′-diphenyldicarboxylate is shown to depend on the nature of the metal (redox-inert Zn(II) or redox-active Ni(II)/Ni(III)). The nickel MO...

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Published in:Theoretical and experimental chemistry 2016-05, Vol.52 (2), p.104-110
Main Authors: Gurtovyi, R. I., Tsymbal, L. V., Kuzmin, R. M., Odynets, I. V., Lampeka, Ya. D.
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Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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container_title Theoretical and experimental chemistry
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Tsymbal, L. V.
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Lampeka, Ya. D.
description The kinetics of the adsorption and desorption of iodine from solution by isostructural metal–organic frameworks formed by macrocyclic nickel or zinc cations and 4,4′-diphenyldicarboxylate is shown to depend on the nature of the metal (redox-inert Zn(II) or redox-active Ni(II)/Ni(III)). The nickel MOF has greater adsorption capacity, while the composite formed by this reaction has electronic conductivity. The observed differences are attributed to the oxidation of nickel(II) to nickel(III) by adsorbed iodine, which leads to formation of iodide or polyiodide anions. On the other hand, in the case of the zinc complex, an adsorption process is not accompanied by redox transformations.
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title Effect of the Redox Properties of the Zinc and Nickel Metal–Organic Frameworks on Peculiarities of Their Interaction with Iodine and the Electronic Conductivity of the Composites Formed
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