Synthesis, crystal structure and properties of copper(II) complexes with triethanolamine and carboxylic acids (succinic, salicylic, cinnamic)

The interaction of triethanolamine (TEA) with Cu(II) salts of salicylic, cinnamic and succinic acids was studied for the first time. The structure of the synthesized complexes was investigated by single-crystal X-ray diffraction. TEA complexes with Cu(II) salicylate ( 1 ) and cinnamate ( 2 ) are bin...

Full description

Saved in:
Bibliographic Details
Published in:Transition metal chemistry (Weinheim) 2020, Vol.45 (1), p.71-81
Main Authors: Kondratenko, Y., Zolotarev, A. A., Ignatyev, I., Ugolkov, V., Kochina, T.
Format: Article
Language:English
Subjects:
Catalysis
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Organometallic Chemistry
Physical Chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The interaction of triethanolamine (TEA) with Cu(II) salts of salicylic, cinnamic and succinic acids was studied for the first time. The structure of the synthesized complexes was investigated by single-crystal X-ray diffraction. TEA complexes with Cu(II) salicylate ( 1 ) and cinnamate ( 2 ) are binuclear mixed ligand complexes, but interaction of TEA with Cu(II) succinate leads to the formation of cationic mononuclear complex—[Cu(TEA) 2 ](C 4 H 4 O 4 ) ( 3 ). Cu(II) complexes 1 – 3 were also characterized by physicochemical and spectroscopic methods. Their antimicrobial activity was investigated.
ISSN:0340-4285
1572-901X
DOI:10.1007/s11243-019-00359-7