A new 3-D Gd-Cu heterometallic polymer [Gd2Cu3（bpy）2- （ip）6]·6H2O with a non-interpenetrated α-Po net

A new 3-D porous Gd-Cu heterometallic polymer [Gd2Cu3（bpy）2- （ip）6]·6H2O （1） （bpy = 2,2′-bipyridine, H2ip = isophthalic acid） has been hydrothermally synthesized and structurally characterized. Compound 1 crystallizes in the triclinic space group P1and displays a 3-D non-interpenetrated α-Po net- wo...

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Bibliographic Details
Published in:Chinese science bulletin 2009-12, Vol.54 (23), p.4272-4276
Main Authors: Jia, XiangLi, Zhou, Jian, Zhao, JunWei, Li, ZhaoHui, Zheng, ShouTian, Yang, GuoYu
Format: Article
Language:English
Subjects:
Chemistry/Food Science
Earth Sciences
Engineering
Humanities and Social Sciences
Inorganic Chemistry
Life Sciences
multidisciplinary
Physics
Science
Science (multidisciplinary)
水热合成
知识产权
联吡啶
聚合物
间苯二甲酸
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Summary:A new 3-D porous Gd-Cu heterometallic polymer [Gd2Cu3（bpy）2- （ip）6]·6H2O （1） （bpy = 2,2′-bipyridine, H2ip = isophthalic acid） has been hydrothermally synthesized and structurally characterized. Compound 1 crystallizes in the triclinic space group P1and displays a 3-D non-interpenetrated α-Po net- work with 1-D channels filled transversely by the hexa-nuclear chain-like （H2O）6. The EPR and thermal stability of 1 were investigated.
ISSN:1001-6538
2095-9273
1861-9541
2095-9281
DOI:10.1007/s11434-009-0549-9