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Free-Standing PEDOT-PSS/Ca3Co4O9 Composite Films as Novel Thermoelectric Materials
Free-standing poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT- PSS)/Ca 3 Co 4 O 9 composite films have been successfully prepared by mechanically blending Ca 3 Co 4 O 9 powder and PEDOT-PSS solution (Baytron P) and casting the mixed solution on polypropylene (PP) film substrates. X-ra...
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Published in: | Journal of electronic materials 2011-05, Vol.40 (5), p.948-952 |
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cites | cdi_FETCH-LOGICAL-c314t-78b54fae9235a08d734d3bebbc27fbb8af2a89ffa771e8b9181b65154022007e3 |
container_end_page | 952 |
container_issue | 5 |
container_start_page | 948 |
container_title | Journal of electronic materials |
container_volume | 40 |
creator | Liu, Congcong Jiang, Fengxing Huang, Mingyu Lu, Baoyang Yue, Ruirui Xu, Jingkun |
description | Free-standing poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT- PSS)/Ca
3
Co
4
O
9
composite films have been successfully prepared by mechanically blending Ca
3
Co
4
O
9
powder and PEDOT-PSS solution (Baytron P) and casting the mixed solution on polypropylene (PP) film substrates. X-ray diffraction (XRD) and scanning electron microscopy (SEM) characterization indicated that the Ca
3
Co
4
O
9
particles were in the shape of sheets and composited well together with PEDOT-PSS. Thermoelectric (TE) measurements revealed that the Seebeck coefficient can be improved by increasing the Ca
3
Co
4
O
9
content in the composite films, with the largest enhancement being 24.8% compared with a free-standing PEDOT-PSS film. However, it is also shown that the power factor of the composite films decreases with increasing Ca
3
Co
4
O
9
content, mainly due to the decline of electrical conductivity and the limited improvement of the Seebeck coefficient. |
doi_str_mv | 10.1007/s11664-010-1465-0 |
format | article |
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3
Co
4
O
9
composite films have been successfully prepared by mechanically blending Ca
3
Co
4
O
9
powder and PEDOT-PSS solution (Baytron P) and casting the mixed solution on polypropylene (PP) film substrates. X-ray diffraction (XRD) and scanning electron microscopy (SEM) characterization indicated that the Ca
3
Co
4
O
9
particles were in the shape of sheets and composited well together with PEDOT-PSS. Thermoelectric (TE) measurements revealed that the Seebeck coefficient can be improved by increasing the Ca
3
Co
4
O
9
content in the composite films, with the largest enhancement being 24.8% compared with a free-standing PEDOT-PSS film. However, it is also shown that the power factor of the composite films decreases with increasing Ca
3
Co
4
O
9
content, mainly due to the decline of electrical conductivity and the limited improvement of the Seebeck coefficient.</description><identifier>ISSN: 0361-5235</identifier><identifier>EISSN: 1543-186X</identifier><identifier>DOI: 10.1007/s11664-010-1465-0</identifier><identifier>CODEN: JECMA5</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Applied sciences ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Conductivity phenomena in semiconductors and insulators ; Electronic transport in condensed matter ; Electronics ; Electronics and Microelectronics ; Exact sciences and technology ; Instrumentation ; Materials ; Materials Science ; Optical and Electronic Materials ; Physics ; Solid State Physics ; Thermoelectric and thermomagnetic effects</subject><ispartof>Journal of electronic materials, 2011-05, Vol.40 (5), p.948-952</ispartof><rights>TMS 2010</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c314t-78b54fae9235a08d734d3bebbc27fbb8af2a89ffa771e8b9181b65154022007e3</citedby><cites>FETCH-LOGICAL-c314t-78b54fae9235a08d734d3bebbc27fbb8af2a89ffa771e8b9181b65154022007e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>309,310,314,780,784,789,790,23930,23931,25140,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24392965$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Congcong</creatorcontrib><creatorcontrib>Jiang, Fengxing</creatorcontrib><creatorcontrib>Huang, Mingyu</creatorcontrib><creatorcontrib>Lu, Baoyang</creatorcontrib><creatorcontrib>Yue, Ruirui</creatorcontrib><creatorcontrib>Xu, Jingkun</creatorcontrib><title>Free-Standing PEDOT-PSS/Ca3Co4O9 Composite Films as Novel Thermoelectric Materials</title><title>Journal of electronic materials</title><addtitle>Journal of Elec Materi</addtitle><description>Free-standing poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT- PSS)/Ca
3
Co
4
O
9
composite films have been successfully prepared by mechanically blending Ca
3
Co
4
O
9
powder and PEDOT-PSS solution (Baytron P) and casting the mixed solution on polypropylene (PP) film substrates. X-ray diffraction (XRD) and scanning electron microscopy (SEM) characterization indicated that the Ca
3
Co
4
O
9
particles were in the shape of sheets and composited well together with PEDOT-PSS. Thermoelectric (TE) measurements revealed that the Seebeck coefficient can be improved by increasing the Ca
3
Co
4
O
9
content in the composite films, with the largest enhancement being 24.8% compared with a free-standing PEDOT-PSS film. However, it is also shown that the power factor of the composite films decreases with increasing Ca
3
Co
4
O
9
content, mainly due to the decline of electrical conductivity and the limited improvement of the Seebeck coefficient.</description><subject>Applied sciences</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Conductivity phenomena in semiconductors and insulators</subject><subject>Electronic transport in condensed matter</subject><subject>Electronics</subject><subject>Electronics and Microelectronics</subject><subject>Exact sciences and technology</subject><subject>Instrumentation</subject><subject>Materials</subject><subject>Materials Science</subject><subject>Optical and Electronic Materials</subject><subject>Physics</subject><subject>Solid State Physics</subject><subject>Thermoelectric and thermomagnetic effects</subject><issn>0361-5235</issn><issn>1543-186X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9UE1LAzEUDKJgrf4Ab3vxGJuXj_04ytqqUN1iK3hbku1L3bIfJVkF_70pKx49DY83M8wMIdfAboGxZOYB4lhSBoyCjBVlJ2QCSgoKafx-SiZMxEAVF-qcXHi_ZwwUpDAhrwuHSNeD7rZ1t4tW8_tiQ1fr9SzXIu9lkUV53x56Xw8YLeqm9ZH20Uv_hU20-UDX9thgNbi6ip71gK7Wjb8kZzYAXv3ilLwt5pv8kS6Lh6f8bkkrAXKgSWqUtBqzEEqzdJsIuRUGjal4Yo1JteU6zazVSQKYmizENbEKnRjnoTGKKYHRt3K99w5teXB1q913Caw8jlKOo5TseIdRShY0N6PmoH2lG-t0V9X-T8ilyHgWq8DjI8-HV7dDV-77T9eFOv-Y_wCse3BO</recordid><startdate>20110501</startdate><enddate>20110501</enddate><creator>Liu, Congcong</creator><creator>Jiang, Fengxing</creator><creator>Huang, Mingyu</creator><creator>Lu, Baoyang</creator><creator>Yue, Ruirui</creator><creator>Xu, Jingkun</creator><general>Springer US</general><general>Springer</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20110501</creationdate><title>Free-Standing PEDOT-PSS/Ca3Co4O9 Composite Films as Novel Thermoelectric Materials</title><author>Liu, Congcong ; Jiang, Fengxing ; Huang, Mingyu ; Lu, Baoyang ; Yue, Ruirui ; Xu, Jingkun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c314t-78b54fae9235a08d734d3bebbc27fbb8af2a89ffa771e8b9181b65154022007e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Applied sciences</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Conductivity phenomena in semiconductors and insulators</topic><topic>Electronic transport in condensed matter</topic><topic>Electronics</topic><topic>Electronics and Microelectronics</topic><topic>Exact sciences and technology</topic><topic>Instrumentation</topic><topic>Materials</topic><topic>Materials Science</topic><topic>Optical and Electronic Materials</topic><topic>Physics</topic><topic>Solid State Physics</topic><topic>Thermoelectric and thermomagnetic effects</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Congcong</creatorcontrib><creatorcontrib>Jiang, Fengxing</creatorcontrib><creatorcontrib>Huang, Mingyu</creatorcontrib><creatorcontrib>Lu, Baoyang</creatorcontrib><creatorcontrib>Yue, Ruirui</creatorcontrib><creatorcontrib>Xu, Jingkun</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of electronic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Congcong</au><au>Jiang, Fengxing</au><au>Huang, Mingyu</au><au>Lu, Baoyang</au><au>Yue, Ruirui</au><au>Xu, Jingkun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Free-Standing PEDOT-PSS/Ca3Co4O9 Composite Films as Novel Thermoelectric Materials</atitle><jtitle>Journal of electronic materials</jtitle><stitle>Journal of Elec Materi</stitle><date>2011-05-01</date><risdate>2011</risdate><volume>40</volume><issue>5</issue><spage>948</spage><epage>952</epage><pages>948-952</pages><issn>0361-5235</issn><eissn>1543-186X</eissn><coden>JECMA5</coden><abstract>Free-standing poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT- PSS)/Ca
3
Co
4
O
9
composite films have been successfully prepared by mechanically blending Ca
3
Co
4
O
9
powder and PEDOT-PSS solution (Baytron P) and casting the mixed solution on polypropylene (PP) film substrates. X-ray diffraction (XRD) and scanning electron microscopy (SEM) characterization indicated that the Ca
3
Co
4
O
9
particles were in the shape of sheets and composited well together with PEDOT-PSS. Thermoelectric (TE) measurements revealed that the Seebeck coefficient can be improved by increasing the Ca
3
Co
4
O
9
content in the composite films, with the largest enhancement being 24.8% compared with a free-standing PEDOT-PSS film. However, it is also shown that the power factor of the composite films decreases with increasing Ca
3
Co
4
O
9
content, mainly due to the decline of electrical conductivity and the limited improvement of the Seebeck coefficient.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s11664-010-1465-0</doi><tpages>5</tpages></addata></record> |
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source | Springer Nature |
subjects | Applied sciences Characterization and Evaluation of Materials Chemistry and Materials Science Condensed matter: electronic structure, electrical, magnetic, and optical properties Conductivity phenomena in semiconductors and insulators Electronic transport in condensed matter Electronics Electronics and Microelectronics Exact sciences and technology Instrumentation Materials Materials Science Optical and Electronic Materials Physics Solid State Physics Thermoelectric and thermomagnetic effects |
title | Free-Standing PEDOT-PSS/Ca3Co4O9 Composite Films as Novel Thermoelectric Materials |
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