Loading…

Free-Standing PEDOT-PSS/Ca3Co4O9 Composite Films as Novel Thermoelectric Materials

Free-standing poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT- PSS)/Ca 3 Co 4 O 9 composite films have been successfully prepared by mechanically blending Ca 3 Co 4 O 9 powder and PEDOT-PSS solution (Baytron P) and casting the mixed solution on polypropylene (PP) film substrates. X-ra...

Full description

Saved in:
Bibliographic Details
Published in:Journal of electronic materials 2011-05, Vol.40 (5), p.948-952
Main Authors: Liu, Congcong, Jiang, Fengxing, Huang, Mingyu, Lu, Baoyang, Yue, Ruirui, Xu, Jingkun
Format: Article
Language:English
Subjects:
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c314t-78b54fae9235a08d734d3bebbc27fbb8af2a89ffa771e8b9181b65154022007e3
cites cdi_FETCH-LOGICAL-c314t-78b54fae9235a08d734d3bebbc27fbb8af2a89ffa771e8b9181b65154022007e3
container_end_page 952
container_issue 5
container_start_page 948
container_title Journal of electronic materials
container_volume 40
creator Liu, Congcong
Jiang, Fengxing
Huang, Mingyu
Lu, Baoyang
Yue, Ruirui
Xu, Jingkun
description Free-standing poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT- PSS)/Ca 3 Co 4 O 9 composite films have been successfully prepared by mechanically blending Ca 3 Co 4 O 9 powder and PEDOT-PSS solution (Baytron P) and casting the mixed solution on polypropylene (PP) film substrates. X-ray diffraction (XRD) and scanning electron microscopy (SEM) characterization indicated that the Ca 3 Co 4 O 9 particles were in the shape of sheets and composited well together with PEDOT-PSS. Thermoelectric (TE) measurements revealed that the Seebeck coefficient can be improved by increasing the Ca 3 Co 4 O 9 content in the composite films, with the largest enhancement being 24.8% compared with a free-standing PEDOT-PSS film. However, it is also shown that the power factor of the composite films decreases with increasing Ca 3 Co 4 O 9 content, mainly due to the decline of electrical conductivity and the limited improvement of the Seebeck coefficient.
doi_str_mv 10.1007/s11664-010-1465-0
format article
fullrecord <record><control><sourceid>pascalfrancis_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1007_s11664_010_1465_0</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>24392965</sourcerecordid><originalsourceid>FETCH-LOGICAL-c314t-78b54fae9235a08d734d3bebbc27fbb8af2a89ffa771e8b9181b65154022007e3</originalsourceid><addsrcrecordid>eNp9UE1LAzEUDKJgrf4Ab3vxGJuXj_04ytqqUN1iK3hbku1L3bIfJVkF_70pKx49DY83M8wMIdfAboGxZOYB4lhSBoyCjBVlJ2QCSgoKafx-SiZMxEAVF-qcXHi_ZwwUpDAhrwuHSNeD7rZ1t4tW8_tiQ1fr9SzXIu9lkUV53x56Xw8YLeqm9ZH20Uv_hU20-UDX9thgNbi6ip71gK7Wjb8kZzYAXv3ilLwt5pv8kS6Lh6f8bkkrAXKgSWqUtBqzEEqzdJsIuRUGjal4Yo1JteU6zazVSQKYmizENbEKnRjnoTGKKYHRt3K99w5teXB1q913Caw8jlKOo5TseIdRShY0N6PmoH2lG-t0V9X-T8ilyHgWq8DjI8-HV7dDV-77T9eFOv-Y_wCse3BO</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Free-Standing PEDOT-PSS/Ca3Co4O9 Composite Films as Novel Thermoelectric Materials</title><source>Springer Nature</source><creator>Liu, Congcong ; Jiang, Fengxing ; Huang, Mingyu ; Lu, Baoyang ; Yue, Ruirui ; Xu, Jingkun</creator><creatorcontrib>Liu, Congcong ; Jiang, Fengxing ; Huang, Mingyu ; Lu, Baoyang ; Yue, Ruirui ; Xu, Jingkun</creatorcontrib><description>Free-standing poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT- PSS)/Ca 3 Co 4 O 9 composite films have been successfully prepared by mechanically blending Ca 3 Co 4 O 9 powder and PEDOT-PSS solution (Baytron P) and casting the mixed solution on polypropylene (PP) film substrates. X-ray diffraction (XRD) and scanning electron microscopy (SEM) characterization indicated that the Ca 3 Co 4 O 9 particles were in the shape of sheets and composited well together with PEDOT-PSS. Thermoelectric (TE) measurements revealed that the Seebeck coefficient can be improved by increasing the Ca 3 Co 4 O 9 content in the composite films, with the largest enhancement being 24.8% compared with a free-standing PEDOT-PSS film. However, it is also shown that the power factor of the composite films decreases with increasing Ca 3 Co 4 O 9 content, mainly due to the decline of electrical conductivity and the limited improvement of the Seebeck coefficient.</description><identifier>ISSN: 0361-5235</identifier><identifier>EISSN: 1543-186X</identifier><identifier>DOI: 10.1007/s11664-010-1465-0</identifier><identifier>CODEN: JECMA5</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Applied sciences ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Conductivity phenomena in semiconductors and insulators ; Electronic transport in condensed matter ; Electronics ; Electronics and Microelectronics ; Exact sciences and technology ; Instrumentation ; Materials ; Materials Science ; Optical and Electronic Materials ; Physics ; Solid State Physics ; Thermoelectric and thermomagnetic effects</subject><ispartof>Journal of electronic materials, 2011-05, Vol.40 (5), p.948-952</ispartof><rights>TMS 2010</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c314t-78b54fae9235a08d734d3bebbc27fbb8af2a89ffa771e8b9181b65154022007e3</citedby><cites>FETCH-LOGICAL-c314t-78b54fae9235a08d734d3bebbc27fbb8af2a89ffa771e8b9181b65154022007e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>309,310,314,780,784,789,790,23930,23931,25140,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=24392965$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Congcong</creatorcontrib><creatorcontrib>Jiang, Fengxing</creatorcontrib><creatorcontrib>Huang, Mingyu</creatorcontrib><creatorcontrib>Lu, Baoyang</creatorcontrib><creatorcontrib>Yue, Ruirui</creatorcontrib><creatorcontrib>Xu, Jingkun</creatorcontrib><title>Free-Standing PEDOT-PSS/Ca3Co4O9 Composite Films as Novel Thermoelectric Materials</title><title>Journal of electronic materials</title><addtitle>Journal of Elec Materi</addtitle><description>Free-standing poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT- PSS)/Ca 3 Co 4 O 9 composite films have been successfully prepared by mechanically blending Ca 3 Co 4 O 9 powder and PEDOT-PSS solution (Baytron P) and casting the mixed solution on polypropylene (PP) film substrates. X-ray diffraction (XRD) and scanning electron microscopy (SEM) characterization indicated that the Ca 3 Co 4 O 9 particles were in the shape of sheets and composited well together with PEDOT-PSS. Thermoelectric (TE) measurements revealed that the Seebeck coefficient can be improved by increasing the Ca 3 Co 4 O 9 content in the composite films, with the largest enhancement being 24.8% compared with a free-standing PEDOT-PSS film. However, it is also shown that the power factor of the composite films decreases with increasing Ca 3 Co 4 O 9 content, mainly due to the decline of electrical conductivity and the limited improvement of the Seebeck coefficient.</description><subject>Applied sciences</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Conductivity phenomena in semiconductors and insulators</subject><subject>Electronic transport in condensed matter</subject><subject>Electronics</subject><subject>Electronics and Microelectronics</subject><subject>Exact sciences and technology</subject><subject>Instrumentation</subject><subject>Materials</subject><subject>Materials Science</subject><subject>Optical and Electronic Materials</subject><subject>Physics</subject><subject>Solid State Physics</subject><subject>Thermoelectric and thermomagnetic effects</subject><issn>0361-5235</issn><issn>1543-186X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9UE1LAzEUDKJgrf4Ab3vxGJuXj_04ytqqUN1iK3hbku1L3bIfJVkF_70pKx49DY83M8wMIdfAboGxZOYB4lhSBoyCjBVlJ2QCSgoKafx-SiZMxEAVF-qcXHi_ZwwUpDAhrwuHSNeD7rZ1t4tW8_tiQ1fr9SzXIu9lkUV53x56Xw8YLeqm9ZH20Uv_hU20-UDX9thgNbi6ip71gK7Wjb8kZzYAXv3ilLwt5pv8kS6Lh6f8bkkrAXKgSWqUtBqzEEqzdJsIuRUGjal4Yo1JteU6zazVSQKYmizENbEKnRjnoTGKKYHRt3K99w5teXB1q913Caw8jlKOo5TseIdRShY0N6PmoH2lG-t0V9X-T8ilyHgWq8DjI8-HV7dDV-77T9eFOv-Y_wCse3BO</recordid><startdate>20110501</startdate><enddate>20110501</enddate><creator>Liu, Congcong</creator><creator>Jiang, Fengxing</creator><creator>Huang, Mingyu</creator><creator>Lu, Baoyang</creator><creator>Yue, Ruirui</creator><creator>Xu, Jingkun</creator><general>Springer US</general><general>Springer</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20110501</creationdate><title>Free-Standing PEDOT-PSS/Ca3Co4O9 Composite Films as Novel Thermoelectric Materials</title><author>Liu, Congcong ; Jiang, Fengxing ; Huang, Mingyu ; Lu, Baoyang ; Yue, Ruirui ; Xu, Jingkun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c314t-78b54fae9235a08d734d3bebbc27fbb8af2a89ffa771e8b9181b65154022007e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Applied sciences</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Conductivity phenomena in semiconductors and insulators</topic><topic>Electronic transport in condensed matter</topic><topic>Electronics</topic><topic>Electronics and Microelectronics</topic><topic>Exact sciences and technology</topic><topic>Instrumentation</topic><topic>Materials</topic><topic>Materials Science</topic><topic>Optical and Electronic Materials</topic><topic>Physics</topic><topic>Solid State Physics</topic><topic>Thermoelectric and thermomagnetic effects</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Congcong</creatorcontrib><creatorcontrib>Jiang, Fengxing</creatorcontrib><creatorcontrib>Huang, Mingyu</creatorcontrib><creatorcontrib>Lu, Baoyang</creatorcontrib><creatorcontrib>Yue, Ruirui</creatorcontrib><creatorcontrib>Xu, Jingkun</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of electronic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Congcong</au><au>Jiang, Fengxing</au><au>Huang, Mingyu</au><au>Lu, Baoyang</au><au>Yue, Ruirui</au><au>Xu, Jingkun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Free-Standing PEDOT-PSS/Ca3Co4O9 Composite Films as Novel Thermoelectric Materials</atitle><jtitle>Journal of electronic materials</jtitle><stitle>Journal of Elec Materi</stitle><date>2011-05-01</date><risdate>2011</risdate><volume>40</volume><issue>5</issue><spage>948</spage><epage>952</epage><pages>948-952</pages><issn>0361-5235</issn><eissn>1543-186X</eissn><coden>JECMA5</coden><abstract>Free-standing poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT- PSS)/Ca 3 Co 4 O 9 composite films have been successfully prepared by mechanically blending Ca 3 Co 4 O 9 powder and PEDOT-PSS solution (Baytron P) and casting the mixed solution on polypropylene (PP) film substrates. X-ray diffraction (XRD) and scanning electron microscopy (SEM) characterization indicated that the Ca 3 Co 4 O 9 particles were in the shape of sheets and composited well together with PEDOT-PSS. Thermoelectric (TE) measurements revealed that the Seebeck coefficient can be improved by increasing the Ca 3 Co 4 O 9 content in the composite films, with the largest enhancement being 24.8% compared with a free-standing PEDOT-PSS film. However, it is also shown that the power factor of the composite films decreases with increasing Ca 3 Co 4 O 9 content, mainly due to the decline of electrical conductivity and the limited improvement of the Seebeck coefficient.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s11664-010-1465-0</doi><tpages>5</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0361-5235
ispartof Journal of electronic materials, 2011-05, Vol.40 (5), p.948-952
issn 0361-5235
1543-186X
language eng
recordid cdi_crossref_primary_10_1007_s11664_010_1465_0
source Springer Nature
subjects Applied sciences
Characterization and Evaluation of Materials
Chemistry and Materials Science
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Conductivity phenomena in semiconductors and insulators
Electronic transport in condensed matter
Electronics
Electronics and Microelectronics
Exact sciences and technology
Instrumentation
Materials
Materials Science
Optical and Electronic Materials
Physics
Solid State Physics
Thermoelectric and thermomagnetic effects
title Free-Standing PEDOT-PSS/Ca3Co4O9 Composite Films as Novel Thermoelectric Materials
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T18%3A43%3A57IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pascalfrancis_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Free-Standing%20PEDOT-PSS/Ca3Co4O9%20Composite%20Films%20as%20Novel%20Thermoelectric%20Materials&rft.jtitle=Journal%20of%20electronic%20materials&rft.au=Liu,%20Congcong&rft.date=2011-05-01&rft.volume=40&rft.issue=5&rft.spage=948&rft.epage=952&rft.pages=948-952&rft.issn=0361-5235&rft.eissn=1543-186X&rft.coden=JECMA5&rft_id=info:doi/10.1007/s11664-010-1465-0&rft_dat=%3Cpascalfrancis_cross%3E24392965%3C/pascalfrancis_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c314t-78b54fae9235a08d734d3bebbc27fbb8af2a89ffa771e8b9181b65154022007e3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true