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Interaction of Short Chain Phenylalkanoic Acids Within Cationic and Anionic Surfactants
Short chain phenylalkanoic acids have been investigated by UV spectroscopy to ascertain their solubilization into cationic surfactant, cetyltrimethylammonium bromide (CTAB), and anionic surfactant, sodium dodecyl sulfate (SDS). The increasing surfactant concentrations caused bathochromic shift in th...
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Published in: | Arabian Journal for Science and Engineering 2012-07, Vol.37 (5), p.1339-1346 |
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container_issue | 5 |
container_start_page | 1339 |
container_title | Arabian Journal for Science and Engineering |
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creator | Naeem, Kashif Shah, S. W. H. Naseem, Bushra Shah, Syed Sakhawat |
description | Short chain phenylalkanoic acids have been investigated by UV spectroscopy to ascertain their solubilization into cationic surfactant, cetyltrimethylammonium bromide (CTAB), and anionic surfactant, sodium dodecyl sulfate (SDS). The increasing surfactant concentrations caused bathochromic shift in the spectra of additive acids. CTAB exhibited greater λ
max
shift, whereas λ
max
values are slightly altered in SDS solution. Moreover, the critical micelle concentration (CMC) of CTAB with and without phenylalkanoic acids was determined by conductivity measurements. The λ
max
and CMC data were used to calculate the electronic transition energy (Δ
E
T
) and Gibbs free energy change of micellization
of CTAB in presence of additive acids. |
doi_str_mv | 10.1007/s13369-012-0240-3 |
format | article |
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max
shift, whereas λ
max
values are slightly altered in SDS solution. Moreover, the critical micelle concentration (CMC) of CTAB with and without phenylalkanoic acids was determined by conductivity measurements. The λ
max
and CMC data were used to calculate the electronic transition energy (Δ
E
T
) and Gibbs free energy change of micellization
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max
shift, whereas λ
max
values are slightly altered in SDS solution. Moreover, the critical micelle concentration (CMC) of CTAB with and without phenylalkanoic acids was determined by conductivity measurements. The λ
max
and CMC data were used to calculate the electronic transition energy (Δ
E
T
) and Gibbs free energy change of micellization
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max
shift, whereas λ
max
values are slightly altered in SDS solution. Moreover, the critical micelle concentration (CMC) of CTAB with and without phenylalkanoic acids was determined by conductivity measurements. The λ
max
and CMC data were used to calculate the electronic transition energy (Δ
E
T
) and Gibbs free energy change of micellization
of CTAB in presence of additive acids.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><doi>10.1007/s13369-012-0240-3</doi><tpages>8</tpages></addata></record> |
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subjects | Engineering Humanities and Social Sciences multidisciplinary Research Article - Chemistry Science |
title | Interaction of Short Chain Phenylalkanoic Acids Within Cationic and Anionic Surfactants |
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