Tin-modified gold-based bulk metallic glasses

• Published in: Gold bulletin 2012-03, Vol.45 (1), p.3-8
• Main Authors: Wang, Shuo-Hong, Chin, Tsung-Shune
• Format: Article
• Language: English
• Subjects: Alloys; Amorphous materials; Boiling; Chemistry and Materials Science; Deformation; Gold; Liquids; Materials Science; Metallic Materials; Original Paper; Stresses; Viscosity
• ISSN: 2190-7579; 0017-1557; 2190-7579
• DOI: 10.1007/s13404-012-0043-z

Tin was selected as a modifying element in low-gold-content (50 at.%) bulk metallic glasses (BMGs) aiming at developing alloys with cost-effective performance. New gold-based Au–Sn–Cu–Si alloys were fabricated by injection-casting into a copper mold. The as-cast BMG Au 50 Sn 6 Cu 26 Si 18 with 18.6-karat gold and a diameter of 1 mm possessed a lower glass transition temperature ( T g ) of 82°C (355 K), a lower liquid temperature of 330°C (603 K), and a super-cooled liquid region of 31°C. The viscosity range of this BMG Au 50 Sn 6 Cu 26 Si 18 was from 10 8 to 10 9  Pa s measured at a low applied stress of 13 kPa. To compare the viscosity with different applied stresses, its viscosity clearly increased with applied stress below T g but not so obvious above T g . The low viscosity of this BMG Au 50 Sn 6 Cu 26 Si 18 at around 102°C, which is very close to the boiling temperature of water (100°C), rendered easy thermal–mechanical deformation in a boiling water-bath by hand-pressing and tweezers-bending. Such a deformation capability in boiling water is beneficial to the further applications in various fields.