Catalytic-assisted synthesis, characterization and low frequency AC conduction of nanostructured conducting polyaniline

• Published in: Iranian polymer journal 2013, Vol.22 (1), p.43-52
• Main Authors: Gopalakrishnan, Kuppusamy, Elango, Muniappan, Ramesh, Chinnathambi, Thamilselvan, Malaiyandi
• Format: Article
• Language: English
• Subjects: Ceramics; Chemistry; Chemistry and Materials Science; Composites; Glass; Natural Materials; Original Paper; Polymer Sciences
• ISSN: 1026-1265; 1735-5265
• DOI: 10.1007/s13726-012-0099-x

Polymerizations of aniline at the reaction temperatures of 25 and 50 °C have been performed in the presence of iron catalyst. The prepared conducting polyaniline at different reaction periods was investigated for physicochemical and electrical properties, through X-ray diffraction (XRD), scanning electron microscopy (SEM), UV–Visible spectroscopy (UV–Vis), Fourier transform infrared spectroscopy (FTIR) and frequency-dependent electrical conductivity measurements, respectively. XRD studies established the improved nanostructured crystalline nature for the polymer prepared at 50 °C. Size of the particles ranging from 10 to 20 nm was calculated for the prepared polyaniline. SEM analysis shows the cauliflower-like morphology for optimized reaction temperature. The study further establishes the attainment of uniform distribution of polyaniline at the reaction temperature of 50 °C. The charge transitions between benzenoid (B-band) and quinonoid (Q-band) bands were witnessed by UV–Vis spectrum analysis. The band gap analysis revealed the narrow band gap direct transition semiconducting nature of the conducting polymer. Quinonoid and phenylene rings were identified through vibrational bands between 1570 and 827 cm −1 via FTIR spectroscopy analysis. The AC conductivity of the sample synthesized at 50 °C showed 1.50 × 10 −1  S cm −1 . Enhancement in conductivity with increasing temperature represented the improved crystalline nature of the polyaniline prepared at 50 °C.