Deamination of cis and trans-aziridines using diethyl thiourea and iodine

Various non-activated aziridines reacted with diethyl thiourea in the presence of iodine in DCM to give the corresponding trans -alkenes as a sole product in good to excellent yields.

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Bibliographic Details
Published in:Journal of the Iranian Chemical Society 2012-10, Vol.9 (5), p.705-708
Main Authors: Samimi, Heshmat A., Shams, Zahra, Momeni, Ahmad R.
Format: Article
Language:English
Subjects:
Analytical Chemistry
Biochemistry
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Organic Chemistry
Original Paper
Physical Chemistry
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Description
Summary:Various non-activated aziridines reacted with diethyl thiourea in the presence of iodine in DCM to give the corresponding trans -alkenes as a sole product in good to excellent yields.
ISSN:1735-207X
1735-2428
DOI:10.1007/s13738-012-0094-3