Solid-state synthesis of zinc oxide nano-structures with similar morphologies to their precursors and metal–organic frameworks topology

The apohost samples of two metal–organic frameworks of [Zn 2 (1,4-bdc) 2 (H 2 O) 2 ·(DMF) 2 ] n ( 1 ·H 2 O·DMF) and [Zn 2 (1,4-bdc) 2 (dabco)]·4DMF· 1 ⁄ 2 H 2 O ( 2 ·H 2 O·DMF), (1,4-bdc = benzene-1,4-dicarboxylate, dabco = 1,4-diazabicyclo[2.2.2] octane and DMF =  N , N -dimethylformamide) were use...

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Bibliographic Details
Published in:Journal of the Iranian Chemical Society 2016-03, Vol.13 (3), p.547-552
Main Authors: Moeinian, Maryam, Akhbari, Kamran
Format: Article
Language:English
Subjects:
Analytical Chemistry
Biochemistry
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Organic Chemistry
Original Paper
Physical Chemistry
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Summary:The apohost samples of two metal–organic frameworks of [Zn 2 (1,4-bdc) 2 (H 2 O) 2 ·(DMF) 2 ] n ( 1 ·H 2 O·DMF) and [Zn 2 (1,4-bdc) 2 (dabco)]·4DMF· 1 ⁄ 2 H 2 O ( 2 ·H 2 O·DMF), (1,4-bdc = benzene-1,4-dicarboxylate, dabco = 1,4-diazabicyclo[2.2.2] octane and DMF =  N , N -dimethylformamide) were used for the preparation of ZnO nanomaterials. [Zn 2 (1,4-bdc) 2 ] ( 1 ) with two-dimensional grids in the crystal structure formed nano-sheet morphology and [Zn 2 (1,4-bdc) 2 (dabco)] ( 2 ) with three-dimensional layered-pillared framework in the crystal structure formed micro-rod morphology. The morphology of the apohost samples has direct influence on the morphology of resulting ZnO nanomaterials and they can be used as templates in the formation of ZnO nanostructures with desirable morphologies.
ISSN:1735-207X
1735-2428
DOI:10.1007/s13738-015-0764-z