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Comparative study of natural and modified Abies bornmulleriana cones in the removal of copper (II) ions
Abies bornmulleriana cones and their modified forms were used to uptake the Cu (II) ions and compare biosorption efficiency and biosorbent capacity. The effect of various experimental conditions on the uptake of the Cu (II) ions was researched. Additionally, Cu (II) ion removal efficiency and capac...
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| Published in: | International journal of environmental science and technology (Tehran) 2022-06, Vol.19 (6), p.5343-5358 |
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| cited_by | cdi_FETCH-LOGICAL-c221t-e8fbbd69b3c43b85dd4de3c27f4a3196bf92f90a43b60a48a2de86749e17d9a33 |
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| cites | cdi_FETCH-LOGICAL-c221t-e8fbbd69b3c43b85dd4de3c27f4a3196bf92f90a43b60a48a2de86749e17d9a33 |
| container_end_page | 5358 |
| container_issue | 6 |
| container_start_page | 5343 |
| container_title | International journal of environmental science and technology (Tehran) |
| container_volume | 19 |
| creator | Oguz, Ensar |
| description | Abies bornmulleriana
cones and their modified forms were used to uptake the Cu (II) ions and compare biosorption efficiency and biosorbent capacity. The effect of various experimental conditions on the uptake of the Cu (II) ions was researched. Additionally, Cu (II) ion removal efficiency and capacity were investigated in the presence of Pb (II) ions. Besides, the Cu (II) ions' removal mechanism was illustrated in terms of FTIR results. Electrophoretic mobilities of the normal and modified cones were determined to get information about the biosorption. The Brunauer, Emmett, and Teller surface area and pore volume per gram of cones before and after biosorption were identified as (5.05 m
2
and 0.0018 cm
3
) and (0.97 m
2
and 0.00032 cm
3
), respectively. The average pore width of the biosorbent before and after the biosorption was calculated as 9.34 and 13.04 Å, respectively. The pseudo-second-order kinetic gave the best fit to the biosorption data (R
2
0.99, 0.99). The biosorption data for the normal and modified biosorbent fitted well to Dubinin–Radushkevitch (D–R) isotherm due to the high
R
2
values (0.99, 0.98), and the maximum biosorption capacities were determined as 16.58 and 25.35 mg g
−1
, respectively. Δ
H
°, Δ
S
°, and Δ
G
° parameters were estimated from the linear plot of ln
Kd
vs. (1/
T
). The normal and modified biosorbent regeneration with 0.5 N HNO
3
showed that the biosorption and desorption processes were reversible. |
| doi_str_mv | 10.1007/s13762-021-03496-8 |
| format | article |
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cones and their modified forms were used to uptake the Cu (II) ions and compare biosorption efficiency and biosorbent capacity. The effect of various experimental conditions on the uptake of the Cu (II) ions was researched. Additionally, Cu (II) ion removal efficiency and capacity were investigated in the presence of Pb (II) ions. Besides, the Cu (II) ions' removal mechanism was illustrated in terms of FTIR results. Electrophoretic mobilities of the normal and modified cones were determined to get information about the biosorption. The Brunauer, Emmett, and Teller surface area and pore volume per gram of cones before and after biosorption were identified as (5.05 m
2
and 0.0018 cm
3
) and (0.97 m
2
and 0.00032 cm
3
), respectively. The average pore width of the biosorbent before and after the biosorption was calculated as 9.34 and 13.04 Å, respectively. The pseudo-second-order kinetic gave the best fit to the biosorption data (R
2
0.99, 0.99). The biosorption data for the normal and modified biosorbent fitted well to Dubinin–Radushkevitch (D–R) isotherm due to the high
R
2
values (0.99, 0.98), and the maximum biosorption capacities were determined as 16.58 and 25.35 mg g
−1
, respectively. Δ
H
°, Δ
S
°, and Δ
G
° parameters were estimated from the linear plot of ln
Kd
vs. (1/
T
). The normal and modified biosorbent regeneration with 0.5 N HNO
3
showed that the biosorption and desorption processes were reversible.</description><identifier>ISSN: 1735-1472</identifier><identifier>EISSN: 1735-2630</identifier><identifier>DOI: 10.1007/s13762-021-03496-8</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aquatic Pollution ; Earth and Environmental Science ; Ecotoxicology ; Environment ; Environmental Chemistry ; Environmental Science and Engineering ; Original Paper ; Soil Science & Conservation ; Waste Water Technology ; Water Management ; Water Pollution Control</subject><ispartof>International journal of environmental science and technology (Tehran), 2022-06, Vol.19 (6), p.5343-5358</ispartof><rights>Islamic Azad University (IAU) 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c221t-e8fbbd69b3c43b85dd4de3c27f4a3196bf92f90a43b60a48a2de86749e17d9a33</citedby><cites>FETCH-LOGICAL-c221t-e8fbbd69b3c43b85dd4de3c27f4a3196bf92f90a43b60a48a2de86749e17d9a33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Oguz, Ensar</creatorcontrib><title>Comparative study of natural and modified Abies bornmulleriana cones in the removal of copper (II) ions</title><title>International journal of environmental science and technology (Tehran)</title><addtitle>Int. J. Environ. Sci. Technol</addtitle><description>Abies bornmulleriana
cones and their modified forms were used to uptake the Cu (II) ions and compare biosorption efficiency and biosorbent capacity. The effect of various experimental conditions on the uptake of the Cu (II) ions was researched. Additionally, Cu (II) ion removal efficiency and capacity were investigated in the presence of Pb (II) ions. Besides, the Cu (II) ions' removal mechanism was illustrated in terms of FTIR results. Electrophoretic mobilities of the normal and modified cones were determined to get information about the biosorption. The Brunauer, Emmett, and Teller surface area and pore volume per gram of cones before and after biosorption were identified as (5.05 m
2
and 0.0018 cm
3
) and (0.97 m
2
and 0.00032 cm
3
), respectively. The average pore width of the biosorbent before and after the biosorption was calculated as 9.34 and 13.04 Å, respectively. The pseudo-second-order kinetic gave the best fit to the biosorption data (R
2
0.99, 0.99). The biosorption data for the normal and modified biosorbent fitted well to Dubinin–Radushkevitch (D–R) isotherm due to the high
R
2
values (0.99, 0.98), and the maximum biosorption capacities were determined as 16.58 and 25.35 mg g
−1
, respectively. Δ
H
°, Δ
S
°, and Δ
G
° parameters were estimated from the linear plot of ln
Kd
vs. (1/
T
). The normal and modified biosorbent regeneration with 0.5 N HNO
3
showed that the biosorption and desorption processes were reversible.</description><subject>Aquatic Pollution</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Science and Engineering</subject><subject>Original Paper</subject><subject>Soil Science & Conservation</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><issn>1735-1472</issn><issn>1735-2630</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kDtPwzAQgC0EEqXwB5g8whDwq048VhWPSJVYYLbs2C6uEjuyk0r99xjameXudHff6fQBcI_RE0aofs6Y1pxUiOAKUSZ41VyABa7pqiKcostzjVlNrsFNznuEGGcML8BuE4dRJTX5g4V5ms0RRgeDmuakeqiCgUM03nlr4Fp7m6GOKQxz39vkVVCwi6E0fYDTt4XJDvFQsHKhi-NoE3xo20foY8i34MqpPtu7c16Cr9eXz817tf14azfrbdURgqfKNk5rw4WmHaO6WRnDjKUdqR1TFAuunSBOIFWGvMRGEWMbXjNhcW2EonQJyOlul2LOyTo5Jj-odJQYyV9V8qRKFlXyT5VsCkRPUC7LYWeT3Mc5hfLnf9QP-cdtrw</recordid><startdate>20220601</startdate><enddate>20220601</enddate><creator>Oguz, Ensar</creator><general>Springer Berlin Heidelberg</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20220601</creationdate><title>Comparative study of natural and modified Abies bornmulleriana cones in the removal of copper (II) ions</title><author>Oguz, Ensar</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c221t-e8fbbd69b3c43b85dd4de3c27f4a3196bf92f90a43b60a48a2de86749e17d9a33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aquatic Pollution</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Science and Engineering</topic><topic>Original Paper</topic><topic>Soil Science & Conservation</topic><topic>Waste Water Technology</topic><topic>Water Management</topic><topic>Water Pollution Control</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Oguz, Ensar</creatorcontrib><collection>CrossRef</collection><jtitle>International journal of environmental science and technology (Tehran)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Oguz, Ensar</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Comparative study of natural and modified Abies bornmulleriana cones in the removal of copper (II) ions</atitle><jtitle>International journal of environmental science and technology (Tehran)</jtitle><stitle>Int. J. Environ. Sci. Technol</stitle><date>2022-06-01</date><risdate>2022</risdate><volume>19</volume><issue>6</issue><spage>5343</spage><epage>5358</epage><pages>5343-5358</pages><issn>1735-1472</issn><eissn>1735-2630</eissn><abstract>Abies bornmulleriana
cones and their modified forms were used to uptake the Cu (II) ions and compare biosorption efficiency and biosorbent capacity. The effect of various experimental conditions on the uptake of the Cu (II) ions was researched. Additionally, Cu (II) ion removal efficiency and capacity were investigated in the presence of Pb (II) ions. Besides, the Cu (II) ions' removal mechanism was illustrated in terms of FTIR results. Electrophoretic mobilities of the normal and modified cones were determined to get information about the biosorption. The Brunauer, Emmett, and Teller surface area and pore volume per gram of cones before and after biosorption were identified as (5.05 m
2
and 0.0018 cm
3
) and (0.97 m
2
and 0.00032 cm
3
), respectively. The average pore width of the biosorbent before and after the biosorption was calculated as 9.34 and 13.04 Å, respectively. The pseudo-second-order kinetic gave the best fit to the biosorption data (R
2
0.99, 0.99). The biosorption data for the normal and modified biosorbent fitted well to Dubinin–Radushkevitch (D–R) isotherm due to the high
R
2
values (0.99, 0.98), and the maximum biosorption capacities were determined as 16.58 and 25.35 mg g
−1
, respectively. Δ
H
°, Δ
S
°, and Δ
G
° parameters were estimated from the linear plot of ln
Kd
vs. (1/
T
). The normal and modified biosorbent regeneration with 0.5 N HNO
3
showed that the biosorption and desorption processes were reversible.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s13762-021-03496-8</doi><tpages>16</tpages></addata></record> |
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| issn | 1735-1472 1735-2630 |
| language | eng |
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| source | Springer Nature |
| subjects | Aquatic Pollution Earth and Environmental Science Ecotoxicology Environment Environmental Chemistry Environmental Science and Engineering Original Paper Soil Science & Conservation Waste Water Technology Water Management Water Pollution Control |
| title | Comparative study of natural and modified Abies bornmulleriana cones in the removal of copper (II) ions |
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