Deuterium isotope effects in the attachment of Hg(6 3P 0) to ammonia, and measurements of the lifetimes of the stabilised complexes

From observations of the decay of the luminescence following the Hg-flash-photosensitised reactions of NH 3 and ND 3, rate coefficients for relaxation of Hg(6 3P 0) were measured in bimolecular collisions and in termolecular collisions chaperoned by N 2 and ammonia. The lifetimes of the stabilised H...

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Bibliographic Details
Published in:Chemical physics letters 1971-01, Vol.8 (5), p.467-469
Main Authors: Koskikallio, J., Callear, A.B., Connor, J.H.
Format: Article
Language:English
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Summary:From observations of the decay of the luminescence following the Hg-flash-photosensitised reactions of NH 3 and ND 3, rate coefficients for relaxation of Hg(6 3P 0) were measured in bimolecular collisions and in termolecular collisions chaperoned by N 2 and ammonia. The lifetimes of the stabilised Hg *-ammonia complexes were also determined. Marked isotope effects were found both in the bi- and termolecular rate coefficients.
ISSN:0009-2614
1873-4448
DOI:10.1016/0009-2614(71)80430-X