Chemically induced electron spin polarisation and radical pair re-encounters

A simple extension of the model of a radical pair is described in which the relative translational motion of the radicals is described by an exponential translational correlation function for departure and re-encounter. A variety of polarisations can be accounted for without invoking re-encounters,...

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Bibliographic Details
Published in:Chemical physics letters 1973-01, Vol.18 (2), p.290-294
Main Author: Atkins, P.W.
Format: Article
Language:English
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Summary:A simple extension of the model of a radical pair is described in which the relative translational motion of the radicals is described by an exponential translational correlation function for departure and re-encounter. A variety of polarisations can be accounted for without invoking re-encounters, although re-encounters can be important in particular situations.
ISSN:0009-2614
1873-4448
DOI:10.1016/0009-2614(73)80439-7