Electron spin emission spectra from pairs of radicals

Electron spin emission from both radicals of a pair has been observed. It is demonstrated that it is possible to explain the polarization by the radical pair mechanism if nuclear relaxation is fast enough. The extent of ST −1 mixing induced by an anisotropic g-factor is deduced.

Saved in:
Bibliographic Details
Published in:Chemical physics letters 1973-01, Vol.22 (1), p.209-211
Main Authors: Atkins, P.W., Dobbs, A.J., McLauchlan, K.A.
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Electron spin emission from both radicals of a pair has been observed. It is demonstrated that it is possible to explain the polarization by the radical pair mechanism if nuclear relaxation is fast enough. The extent of ST −1 mixing induced by an anisotropic g-factor is deduced.
ISSN:0009-2614
1873-4448
DOI:10.1016/0009-2614(73)80572-X