Measurement of spin-lattice relaxation times of triplet states in fluid solution

A technique is reported for measuring triplet spin-lattice relaxation times in fluid solution. It is based on the observation of chemically induced electron spin polarization, in the presence of a triplet quencher. Spin-lattice relaxation times of the order of 10 ns are reported for the duroquinone...

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Bibliographic Details
Published in:Chemical physics letters 1974-12, Vol.29 (4), p.616-617
Main Authors: Atkins, P.W., Dobbs, A.J., McLauchlan, K.A.
Format: Article
Language:English
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Summary:A technique is reported for measuring triplet spin-lattice relaxation times in fluid solution. It is based on the observation of chemically induced electron spin polarization, in the presence of a triplet quencher. Spin-lattice relaxation times of the order of 10 ns are reported for the duroquinone triplet in various solvents.
ISSN:0009-2614
1873-4448
DOI:10.1016/0009-2614(74)85104-3