Laser induced photochemical enrichment of chlorine isotopes

Chlorine isotopic abundances were significantly altered by laser induced, selective excitation of particular isotopic species of thiophosgene followed by a chemical reaction between the electronically excited thiophosgene and diethoxyethylene. The concentration of 35Cl in thiophosgene was changed fr...

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Bibliographic Details
Published in:Chemical physics letters 1975-01, Vol.30 (2), p.165-170
Main Authors: Lamotte, Michel, Dewey, Harry J., Keller, Richard A., Ritter, Joseph J.
Format: Article
Language:English
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Summary:Chlorine isotopic abundances were significantly altered by laser induced, selective excitation of particular isotopic species of thiophosgene followed by a chemical reaction between the electronically excited thiophosgene and diethoxyethylene. The concentration of 35Cl in thiophosgene was changed from 75% to 64% or 80% depending upon the isotopic species initially excited.
ISSN:0009-2614
1873-4448
DOI:10.1016/0009-2614(75)80093-5