Intermolecular coupling of the CO stretching vibrations in liquid acetone: an isotopic dilution study

The separation Δ v between the isotropic and anisotropic component of the CO stretching Raman band was studied in mixtures of acetone- 16O and acetone- 18O. An explanation is proposed for the observed invariance of the aniso tropic frequency. The isotropic bandwidth and the concentration threshold...

Full description

Saved in:
Bibliographic Details
Published in:Chemical physics letters 1980-01, Vol.75 (2), p.287-289
Main Authors: Kamoun, Mohamed, Mirone, Paolo
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The separation Δ v between the isotropic and anisotropic component of the CO stretching Raman band was studied in mixtures of acetone- 16O and acetone- 18O. An explanation is proposed for the observed invariance of the aniso tropic frequency. The isotropic bandwidth and the concentration threshold for the appearance of Δ v are discussed.
ISSN:0009-2614
1873-4448
DOI:10.1016/0009-2614(80)80515-X