SW Xα calculations and x-ray photoelectron spectra of molybdenum(II) chloride cluster compounds

X-ray photoelectron spectra of the [Mo 6Cl 8]Cl 4 cluster compound have been measured and discussed. For the interpretation of the valence band spectrum several SW Xα calculations have been performed. Comparison between calculated and experimental spectra illustrates the importance of covalent Mo-Cł...

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Bibliographic Details
Published in:Chemical physics letters 1980-01, Vol.75 (2), p.373-377
Main Authors: Seifert, G., Finster, J., Müller, H.
Format: Article
Language:English
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Summary:X-ray photoelectron spectra of the [Mo 6Cl 8]Cl 4 cluster compound have been measured and discussed. For the interpretation of the valence band spectrum several SW Xα calculations have been performed. Comparison between calculated and experimental spectra illustrates the importance of covalent Mo-Cł bonding for the stability of the cluster.
ISSN:0009-2614
1873-4448
DOI:10.1016/0009-2614(80)80534-3