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CIDNP studies of biradicals in super-high magnetic fields

1H and13C CIDNP effects in short 1–5, 1–6 and 1–7 biradicals under photolysis of cyclic aliphatic ketones in a 47 kG magnetic field of an XL-200 NMR spectrometer have been investigated in solution and in the gas phase. The results obtained have been interpreted in terms of the S–T-mechanism of CIDNP...

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Bibliographic Details
Published in:Chemical physics letters 1984-02, Vol.104 (2-3), p.284-289
Main Authors: Yurkovskaya, A.V., Obynochny, A.A., Sagdeev, R.Z.
Format: Article
Language:English
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Summary:1H and13C CIDNP effects in short 1–5, 1–6 and 1–7 biradicals under photolysis of cyclic aliphatic ketones in a 47 kG magnetic field of an XL-200 NMR spectrometer have been investigated in solution and in the gas phase. The results obtained have been interpreted in terms of the S–T-mechanism of CIDNP effects.
ISSN:0009-2614
1873-4448
DOI:10.1016/0009-2614(84)80212-2