Rovibrational analysis of the v15 band in the HCN---HF hydrogen bonded cluster

The observation and assignment of rotational structure in the v 1 5 fundamental, the HCN intramolecular bending vibration, of the HCN---HF hydrogen bonded complex is reported, and the rotational constants have been derived. All intramolecular vibrations in this dimer have now been studied, and the f...

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Bibliographic Details
Published in:Chemical physics letters 1986-03, Vol.124 (6), p.579-582
Main Authors: Wofford, B.A., Bevan, J.W., Olson, W.B., Lafferty, W.J.
Format: Article
Language:English
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Summary:The observation and assignment of rotational structure in the v 1 5 fundamental, the HCN intramolecular bending vibration, of the HCN---HF hydrogen bonded complex is reported, and the rotational constants have been derived. All intramolecular vibrations in this dimer have now been studied, and the frequency shifts of these vibrations upon complex formation have been obtained. The results are compared with the predictions of ab initio molecular orbital calculations.
ISSN:0009-2614
1873-4448
DOI:10.1016/0009-2614(86)85080-1