Inter- and intra-molecular radical cations of alkyl bromides in aqueous solution

The transient optical absorption bands with λ max=410 and 385 nm, formed on OH radical-induced reaction with ethyl bromide and 1,3-dibromopropane in 6.5 mol dm −3 perchloric acid have been assigned to inter- and intra-molecular radical cations, respectively.

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Bibliographic Details
Published in:Chemical physics letters 1992-06, Vol.194 (1), p.135-138
Main Authors: Mohan, H., Maity, D.K., Mittal, J.P.
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Free radicals chemistry
Organic chemistry
Reactivity and mechanisms
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Description
Summary:The transient optical absorption bands with λ max=410 and 385 nm, formed on OH radical-induced reaction with ethyl bromide and 1,3-dibromopropane in 6.5 mol dm −3 perchloric acid have been assigned to inter- and intra-molecular radical cations, respectively.
ISSN:0009-2614
1873-4448
DOI:10.1016/0009-2614(92)85755-Y