Catalytic asymmetric oxidations using optically active (salen)manganese(III) complexes as catalysts

This review deals with enantioselective one oxygen atom transfer reactions (epoxidation, oxidation of enolates, and oxidation of sulphide to sulphoxides) catlaysed by optically active (salen)manganese(III)complexes. Asymmetric aziridination is also discussed briefly.

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Bibliographic Details
Published in:Coordination chemistry reviews 1995-03, Vol.140, p.189-214
Main Author: Katsuki, Tsutomu
Format: Article
Language:English
Subjects:
(Salen)manganese(III)
Catalysis
Optical activity
Oxidation
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Summary:This review deals with enantioselective one oxygen atom transfer reactions (epoxidation, oxidation of enolates, and oxidation of sulphide to sulphoxides) catlaysed by optically active (salen)manganese(III)complexes. Asymmetric aziridination is also discussed briefly.
ISSN:0010-8545
1873-3840
DOI:10.1016/0010-8545(94)01124-T