Thermal diffusion studies by emf technique

The emf of non-isothermal cells due to thermal diffusion has been determined for cadmium iodide in water, formamide and methyl formamide, by using cadmium amalgam as the reversible electrodes. The results are interpreted in terms of the structure of the solvents. Détermination de la f.e.m., provenan...

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Bibliographic Details
Published in:Electrochimica acta 1972, Vol.17 (1), p.63-66
Main Author: Blokhra, R.L.
Format: Article
Language:English
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Summary:The emf of non-isothermal cells due to thermal diffusion has been determined for cadmium iodide in water, formamide and methyl formamide, by using cadmium amalgam as the reversible electrodes. The results are interpreted in terms of the structure of the solvents. Détermination de la f.e.m., provenant de la diffusion thermique, de cellules anisothermes, dans le cas de l'iodure de cadmium dans l'eau, la formamide et la méthylformamide, en utilisant l'amalgame au cadmium comme électrode réversible. Les résultats sont interprétés en terme de structure des solvants. Die emf von nicht-isothermischen Zellen infolge thermischer Diffusion ist für Kadmiumjodid in Wasser, Formamid und Methylformamid bei Verwendung von Kadmiumamalgam als umkehrbare Elektroden bestimmt worden. Die Ergebnisse werden in Form der Struktur der Lösungen gedeutet.
ISSN:0013-4686
1873-3859
DOI:10.1016/0013-4686(72)85007-2