On selection of standard states in adsorption isotherms

The question of choice of appropriate standard states for adsorbed phases at electrode interfaces is reviewed and examined in relation to solvent displacement and the Langmuir and Flory-Huggins types of adsorption isotherms. Comparison with the situation for gas/solid adsorption is made. Standard po...

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Bibliographic Details
Published in:Electrochimica acta 1974-01, Vol.19 (8), p.455-460
Main Authors: Conway, B.E., Angerstein-Kozlowska, H., Dhar, H.P.
Format: Article
Language:English
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Summary:The question of choice of appropriate standard states for adsorbed phases at electrode interfaces is reviewed and examined in relation to solvent displacement and the Langmuir and Flory-Huggins types of adsorption isotherms. Comparison with the situation for gas/solid adsorption is made. Standard potentials for electrochemisorption are considered for electrochemical isotherms with and without interaction/heterogeneity terms.
ISSN:0013-4686
1873-3859
DOI:10.1016/0013-4686(74)87024-6