Ion association of (1:1) electrolytes in pure alcohols at 25°C

Conductances of S-n-buis Br, S-n-amis Br, S-meis I, S-n-buis I, S-n-amis-I, S-n-heptis I, S-n-pris Pi, S-n-buis Pi, S-n-amis Pi and S-n-heptis Pi are reported in EtOH, n-PrOH and n-BuOH. The results are analyzed using the Fuoss and Onsager equation (1959) to obtain the three characteristic parameter...

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Bibliographic Details
Published in:Electrochimica acta 1979, Vol.24 (9), p.957-967
Main Authors: Hafez, Amina M., Sadek, H., Ramadan, M.Sh
Format: Article
Language:English
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Summary:Conductances of S-n-buis Br, S-n-amis Br, S-meis I, S-n-buis I, S-n-amis-I, S-n-heptis I, S-n-pris Pi, S-n-buis Pi, S-n-amis Pi and S-n-heptis Pi are reported in EtOH, n-PrOH and n-BuOH. The results are analyzed using the Fuoss and Onsager equation (1959) to obtain the three characteristic parameters; conductance at infinite dilution Λ 0, contact distance å and association constant K A. The results are also analyzed using Fuoss' equation (1975-1977), from which the true values of Λ 0, the cosphere diameter R and K A are obtained.
ISSN:0013-4686
1873-3859
DOI:10.1016/0013-4686(79)87093-0