The electrochemical cleavage of protecting groups

An overview of the possibilities for the electrochemical removal of protecting groups is given and it is concluded that electrochemical methods might be very appropriate and convenient for carrying out selective deprotection; there is, however, a need for further work to demonstrate conditions where...

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Bibliographic Details
Published in:Electrochimica Acta 1986-06, Vol.31 (6), p.607-620
Main Author: Montenegro, M.I.
Format: Article
Language:English
Subjects:
Catalysis
Catalysts: preparations and properties
Catalytic reactions
Chemistry
Exact sciences and technology
General and physical chemistry
General. Nomenclature, chemical documentation, computer chemistry
Theory of reactions, general kinetics
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Summary:An overview of the possibilities for the electrochemical removal of protecting groups is given and it is concluded that electrochemical methods might be very appropriate and convenient for carrying out selective deprotection; there is, however, a need for further work to demonstrate conditions where yields are truly >99%, to define convenient procedures and to use to the full the potential of electrochemistry to give selective cleavage even when the molecule is polyprotected.
ISSN:0013-4686
1873-3859
DOI:10.1016/0013-4686(86)87027-X